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Ch.15 - Chemical Equilibrium

Chapter 15, Problem 77

Which of the following reactions yield appreciable equilib- rium concentrations of both reactants and products? (a) 2 Cu1s2 + O21g2 ∆ 2 CuO1s2; Kc = 4 * 1045

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Hello everyone today. We have the following problem identify which gives a comparable concentration of products and reaction reactant at equilibrium. So before we do that we want to recall that K. C. Or the equilibrium constant can be used to determine the extent of a reaction. And give us an idea of the relative amounts of our reactant or the concentration of our reactant and the concentration of our products. And so if we look at option A here and we see this reaction with the following equilibrium constant. We note that the equilibrium constant is very small. It's some number two. The -48. That is a very small number. And so since it is very small The reverse reaction is going to be favored. So it's going to be favored in this direction which is going to be forming more gaseous water or H20. And so the equally mixture, the equilibrium mixture is going to contain mostly the reactor which is water. And so Andrew is actually not going to be our answer. If we look at answer choice B. Answer choice B is the exact opposite of answer choice A. The equilibrium constant is very large. Write this number to the 10 times or 10 to the 31st power is a very very large number. And so that means that the equilibrium is going to favor the forward direction. So it's going to form or favor the hydrochloric acid production. So it's going to be mostly on the products with mostly favoring products. So that cannot be representative of equilibrium. However, if we look at answer choice C, we have a moderate equilibrium constant, and so this is going to be the closest or the best representation of equilibrium. And so with that we've answered the question as answer choice C. Overall, I hope this helped, and until next time.
Related Practice
Textbook Question

The reaction 2 AsH31g2 ∆ As21g2 + 3 H21g2 has Kp = 7.2 * 107 at 1073 K. At the same temperature, what is Kp for each of the following reactions? (a) As21g2 + 3 H21g2 ∆ 2 AsH31g2

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Textbook Question
The vapor pressure of water at 25 °C is 0.0313 atm. Cal- culate the values of Kp and Kc at 25 °C for the equilibrium H2O1l2 ∆ H2O1g2.
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Textbook Question
For each of the following equilibria, write the equilibrium constant expression for Kc. Where appropriate, also write the equilibrium constant expression for Kp. (a) Fe2O31s2 + 3 CO1g2 ∆ 2 Fe1l2 + 3 CO21g2
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Textbook Question
The value of Kc for the reaction 3 O21g2 ∆ 2 O31g2 is 1.7 * 10-56 at 25°C. Do you expect pure air at 25 °C to contain much O3 (ozone) when O2 and O3 are in equilib- rium? If the equilibrium concentration of O2 in air at 25 °C is 8 * 10-3 M, what is the equilibrium concentration of O3?
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Textbook Question
Calculate the equilibrium concentrations at 25 °C for the reaction in Problem 15.84 if the initial concentrations are 3N2O44 = 0.0200 M and 3NO24 = 0.0300 M.
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Textbook Question
The industrial solvent ethyl acetate is produced by the reac-tion of acetic acid with ethanol: CH3CO2H1soln2 + CH3CH2OH1soln2 ∆ CH3CO2CH2CH31soln2 + H2O1soln2 Ethyl acetate (b) A solution prepared by mixing 1.00 mol of acetic acid and 1.00 mol of ethanol contains 0.65 mol of ethyl ace- tate at equilibrium. Calculate the value of Kc. Explain why you can calculate K without knowing the volume of the solution.
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