Ch.15 - Chemical Equilibrium
Chapter 15, Problem 96
The value of Kc for the reaction of acetic acid with ethanol is 3.4 at 25°C: CH3CO2H1soln2 + CH3CH2OH1soln2 ∆ Acetic acid Ethanol CH3CO2CH2CH31soln2 + H2O1soln2 Kc = 3.4 (a) How many moles of ethyl acetate are present in an equi- librium mixture that contains 4.0 mol of acetic acid, 6.0 mol of ethanol, and 12.0 mol of water at 25 °C?
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Related Practice
Textbook Question
The following reaction, which has Kc = 0.145 at 298 K, takes place in carbon tetrachloride solution:
2 BrCl1soln2 ∆ Br21soln2 + Cl21soln2 A measurement of the concentrations shows 3BrCl4 =
0.050 M, 3Br24 = 0.035 M, and 3Cl24 = 0.030 M. (b) Determine the equilibrium concentrations of BrCl, Br1, and Cl2.
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Textbook Question
An equilibrium mixture of N2, H2, and NH3 at 700 K con- tains 0.036 M N2 and 0.15 M H2. At this temperature, Kc for the reaction N21g2 + 3 H21g2 ∆ 2 NH31g2 is 0.29. What is the concentration of NH3?
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Textbook Question
Recalculate the equilibrium concentrations in Problem 15.93 if the initial concentrations are 2.24 M N2 and 0.56 M O2. (This N2>O2 concentration ratio is the ratio found in air.)
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Textbook Question
At 1000 K, the value of Kc for the reaction C1s2 + H2O1g2 ∆ CO1g2 + H21g2 is 3.0 * 10-2. Calculate the equilibrium concentrations of H2O, CO2, and H2 in a reac-
tion mixture obtained by heating 6.00 mol of steam and an excess of solid carbon in a 5.00-L container. What is the molar composition of the equilibrium mixture?
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Textbook Question
At 100 °C, Kc = 4.72 for the reaction 2 NO21g2 ∆ N2O41g2. An empty 10.0-L flask is filled with 4.60 g of NO2 at 100 °C. What is the total pressure in the flask at equilibrium?
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Textbook Question
The equilibrium constant Kc for the reaction N21g2 + 3 H21g2 ∆ 2 NH31g2 is 4.20 at 600 K. When a quantity of gaseous NH3 was placed in a 1.00-L reaction vessel at
600 K and the reaction was allowed to reach equilibrium, the vessel was found to contain 0.200 mol of N2. How many moles of NH3 were placed in the vessel?
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