Ch.15 - Chemical Equilibrium
Chapter 15, Problem 45
Consider the reaction A + B ∆ AB. The vessel on the right contains an equilibrium mixture of A molecules (red spheres), B molecules (blue spheres), and AB molecules. If the stopcock is opened and the contents of the two vessels are allowed to mix, will the reaction go in the forward or reverse direction? Explain.
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Related Practice
Textbook Question
Consider the interconversion of A molecules (red spheres) and B molecules (blue spheres) according to the reaction A ∆ B. Each of the series of pictures at the right represents a separate experiment in which time increases from left to right:
(b) What is the value of the equilibrium constant Kc for the reaction A ∆ B?
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Textbook Question
The reaction A2 + B ∆ A + AB has an equilibrium con-stant Kc = 2. The following pictures represent reaction mix- tures that contain A atoms (red), B atoms (blue), and A2 and AB molecules. (a) Which reaction mixture is at equilibrium?
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Textbook Question
The following pictures represent the initial state and the equilibrium state for the reaction of A2 molecules (red) with B atoms (blue) to give AB molecules. (a) Write a balanced chemical equation for the reaction.
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Textbook Question
The following pictures represent the composition of the equi- librium mixture for the reaction A + B ∆ AB at 300 K and at 400 K. Is the reaction exothermic or endothermic? Explain using Le Châtelier's principle.
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Textbook Question
The following picture represents the composition of the equi- librium mixture for the endothermic reaction A2 ∆ 2 A at 500 K. Draw a picture that represents the equilibrium mixture after each of the following changes.
(b) Increasing the volume
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Textbook Question
The following picture represents the equilibrium state for the reaction 2 AB ∆ A2 + B2. Which rate constant is larger, kf or kr? Explain.
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