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Ch.15 - Chemical Equilibrium
Chapter 15, Problem 124

Consider the exothermic reaction CoCl 2-1aq2 + 6 H O1l2 ∆ Co1H O2 2 + 1aq2 + 4 Cl-1aq2 which interconverts the blue CoCl 2- ion and the pink Co 2 +CoCl 2- increase or decrease when the following changes occur?(c) The solution is diluted with water.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Le Chatelier's Principle

Le Chatelier's Principle states that if a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium shifts to counteract the change. In the context of the given reaction, diluting the solution with water alters the concentration of the reactants and products, prompting the system to adjust in a way that minimizes the effect of dilution.
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Exothermic Reactions

Exothermic reactions are chemical processes that release heat to the surroundings. In the provided reaction, the formation of Co(H2O)6^2+ and Cl^- ions from CoCl2 and water is exothermic, meaning that the reaction releases energy. Understanding this helps predict how temperature changes can affect the equilibrium position.
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Color Change in Coordination Complexes

The color change observed in coordination complexes, such as the transition from blue CoCl2^- to pink Co(H2O)6^2+, is due to the different ligands surrounding the metal ion. The nature of the ligands and their arrangement affects the d-orbital splitting, which in turn influences the absorption of light and the perceived color. This concept is crucial for interpreting the effects of dilution on the equilibrium state.
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Related Practice
Textbook Question

Consider the following equilibrium: Ag+ (aq) + Cl-(aq) → AgCl(s) Use Le Châtelier's principle to predict how the amount of solid silver chloride will change when the equilibrium is disturbed by: (c) Adding NO3, which reacts with Ag+ to form the complex ion Ag(NH3)2+

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Textbook Question

Consider the following equilibrium: Ag+(aq) + Cl-(aq) ⇌ AgCl(s) Use Le Châtelier's principle to predict how the amount of solid silver chloride will change when the equilibrium is disturbed by: (d) Removing Cl-; also account for the change using the reaction quotient Qc

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Textbook Question
For the water–gas shift reaction CO1g2 + H2O1g2 ∆ CO21g2 + H21g2, ΔH° = - 41.2 kJ does the amount of H2 in an equilibrium mixture increase or decrease when the temperature is increased? How does Kc change when the temperature is decreased? Justify your answers using Le Châtelier's principle.
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Textbook Question
The following reaction is important in gold mining: 4 Au1s2 + 8 CN-1aq2 + O21g2 + 2 H2O1l2 ∆ 4 Au1CN22-1aq2 + 4 OH-1aq2For a reaction mixture at equilibrium, in which direction would the reaction go to reestablish equilibrium after each of the following changes? (a) Adding gold
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Textbook Question
The equilibrium constant Kp for the reaction PCl51g2 ∆ PCl31g2 + Cl21g2 is 3.81 * 102 at 600 K and 2.69 * 103 at 700 K. (b) How are the equilibrium amounts of reactants and products affected by (iii) addition of a catalyst?
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Textbook Question
Baking soda (sodium bicarbonate) decomposes when it is heated: 2 NaHCO31s2 ∆ Na2CO31s2 + CO21g2 + H2O1g2 ΔH° = + 136 kJ Consider an equilibrium mixture of reactants and products in a closed container. How does the number of moles of CO2 change when the mixture is disturbed by the following: (b) Adding water vapor
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