Ch.14 - Chemical Kinetics
Chapter 14, Problem 117
Why doesn't a catalyst appear in the overall chemical equation for a reaction?
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Related Practice
Textbook Question
A proposed mechanism for the oxidation of nitric oxide to nitrogen dioxide was described in Problem 14.29. Another possible mechanism for this reaction is
(b) Show that this mechanism is consistent with the experimental rate law, Rate = k[NO4][O2].
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Textbook Question
A proposed mechanism for the oxidation of nitric oxide to nitrogen dioxide was described in Problem 14.29. Another possible mechanism for this reaction is
(c) Relate the rate constant k to the rate constants for the elementary reactions.
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Textbook Question
Comment on the following statement: 'A catalyst increases
the rate of a reaction, but it is not consumed because it
does not participate in the reaction.'
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Textbook Question
Consider the following mechanism for the decomposition
of nitramide 1NH2NO22 in aqueous solution:
NH2NO21aq2 + OH-1aq2S NHNO2
-1aq2 + H2O1l2
NHNO2
-1aq2S N2O1g2 + OH-1aq2
(c) How will the rate of the overall reaction be affected if
HCl is added to the solution?
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Textbook Question
In Problem 14.113, you wrote a mechanism for the nitric oxide–
facilitated decomposition of ozone. Does your mechanism
involve a catalyst or a reaction intermediate? Explain.
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Textbook Question
The rate of the reaction A + B2 S AB + B is directly proportional
to the concentration of B2, independent of the
concentration of A, and directly proportional to the concentration
of a substance C.
(c) What is the role of C in this reaction? Why doesn't C
appear in the chemical equation for the overall reaction?
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