Ch.14 - Chemical Kinetics
Chapter 14, Problem 120
Consider the following mechanism for the decomposition of nitramide 1NH2NO22 in aqueous solution: NH2NO21aq2 + OH-1aq2S NHNO2 -1aq2 + H2O1l2 NHNO2 -1aq2S N2O1g2 + OH-1aq2 (c) How will the rate of the overall reaction be affected if HCl is added to the solution?
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Related Practice
Textbook Question
A proposed mechanism for the oxidation of nitric oxide to nitrogen dioxide was described in Problem 14.29. Another possible mechanism for this reaction is
(c) Relate the rate constant k to the rate constants for the elementary reactions.
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Textbook Question
Comment on the following statement: 'A catalyst increases
the rate of a reaction, but it is not consumed because it
does not participate in the reaction.'
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Textbook Question
Why doesn't a catalyst appear in the overall chemical equation
for a reaction?
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Textbook Question
In Problem 14.113, you wrote a mechanism for the nitric oxide–
facilitated decomposition of ozone. Does your mechanism
involve a catalyst or a reaction intermediate? Explain.
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Textbook Question
The rate of the reaction A + B2 S AB + B is directly proportional
to the concentration of B2, independent of the
concentration of A, and directly proportional to the concentration
of a substance C.
(c) What is the role of C in this reaction? Why doesn't C
appear in the chemical equation for the overall reaction?
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Textbook Question
Consider the reaction H2(g) + I2(g) → 2 HI(g). The reaction of a fixed amount of H2 and I2 is studied in a cylinder fitted with a movable piston. Indicate the effect of each of the following changes on the rate of the reaction. (a) An increase in temperature at constant volume
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