Ch.14 - Chemical Kinetics
Chapter 14, Problem 105
What distinguishes the rate-determining step from the other steps in a reaction mechanism? How does the ratedetermining step affect the observed rate law?
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Related Practice
Textbook Question
If the rate of a reaction increases by a factor of 2.5 when the
temperature is raised from 20 °C to 30 °C, what is the value
of the activation energy in kJ/mol? By what factor does the
rate of this reaction increase when the temperature is raised
from 120 °C to 130 °C?
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Textbook Question
You wish to determine the activation energy for the following
first-order reaction:
AS B + C
(b) How would you use these data to determine the activation
energy?
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Textbook Question
What is the relationship between the coefficients in a balanced
chemical equation for an overall reaction and the
exponents in the rate law?
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Textbook Question
Consider the following mechanism for the reaction of
hydrogen and iodine monochloride:
Step 1. H21g2 + ICl1g2S HI1g2 + HCl1g2
Step 2. HI1g2 + ICl1g2S I21g2 + HCl1g2
(b) Identify any reaction intermediates.
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Textbook Question
The thermal decomposition of nitryl chloride, NO2Cl, is
believed to occur by the following mechanism:
NO2Cl1g2 ¡ k1 NO21g2 + Cl1g2
Cl1g2 + NO2Cl1g2 ¡ k2 NO21g2 + Cl21g2
(c) What rate law is predicted by this mechanism if the first
step is rate-determining?
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Textbook Question
A proposed mechanism for the oxidation of nitric oxide to nitrogen dioxide was described in Problem 14.29. Another possible mechanism for this reaction is
(a) Write a balanced equation for the overall reaction.
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