Ch.14 - Chemical Kinetics
Chapter 14, Problem 98
If the rate of a reaction increases by a factor of 2.5 when the temperature is raised from 20 °C to 30 °C, what is the value of the activation energy in kJ/mol? By what factor does the rate of this reaction increase when the temperature is raised from 120 °C to 130 °C?
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Related Practice
Textbook Question
Consider three reactions with different values of Ea and ΔE:
Reaction 1. Ea = 20 kJ>mol; ΔE = -60 kJ/mol
Reaction 2. Ea = 10 kJ>mol; ΔE = -20 kJ/mol
Reaction 3. Ea = 40 kJ>mol; ΔE = +15 kJ/mol
(b) Assuming that all three reactions are carried out at the same temperature and that all three have the same frequency factor A, which reaction is the fastest and which is the slowest?
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Textbook Question
Consider three reactions with different values of Ea and ΔE:
Reaction 1. Ea = 20 kJ>mol; ΔE = -60 kJ/mol
Reaction 2. Ea = 10 kJ>mol; ΔE = -20 kJ/mol
Reaction 3. Ea = 40 kJ>mol; ΔE = +15 kJ/mol
(c) Which reaction is the most endothermic, and which is the most exothermic?
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Textbook Question
A certain first-order reaction has a rate constant of
1.0 * 10-3 s-1 at 25 °C.
(b) What is the Ea (in kJ/mol) if the same temperature
change causes the rate to triple?
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Textbook Question
You wish to determine the activation energy for the following
first-order reaction:
AS B + C
(b) How would you use these data to determine the activation
energy?
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Textbook Question
What is the relationship between the coefficients in a balanced
chemical equation for an overall reaction and the
exponents in the rate law?
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Textbook Question
What distinguishes the rate-determining step from the
other steps in a reaction mechanism? How does the ratedetermining
step affect the observed rate law?
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