Ch.13 - Solutions & Their Properties
Chapter 13, Problem 123
If cost per gram were not a concern, which of the following substances would be the most efficient per unit mass for melting snow from sidewalks and roads: glucose 1C6H12O62, LiCl, NaCl, or CaCl2? Explain.
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Textbook Question
What osmotic pressure in mm Hg would you expect for an aqueous solution of 11.5 mg of insulin 1mol. weight = 59902
in 6.60 mL of solution at 298 K? What would the height of the water column be in meters? The density of mercury is
13.534 g/mL at 298 K.
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Textbook Question
Human blood gives rise to an osmotic pressure of approxi-mately 7.7 atm at body temperature, 37.0 °C. What must the molarity of an intravenous glucose solution be to give rise to the same osmotic pressure as blood?
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Textbook Question
13.122 When salt is spread on snow-covered roads at - 2 °C, the snow melts. When salt is spread on snow-covered roads at
- 30 °C, nothing happens. Explain.
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Textbook Question
Bromine is sometimes used as a solution in tetrachloro- methane, CCl4. What is the vapor pressure in mm Hg of a solution of 1.50 g of Br2 in 145.0 g of CCl4 at 300 K? The vapor pressure of pure bromine at 300 K is 30.5 kPa, and the vapor pressure of CCl4 is 16.5 kPa.
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Textbook Question
There's actually much more in seawater than just dissolved NaCl. Major ions present include 19,000 ppm Cl-, 10,500 ppm Na+, 2650 ppm SO 2-, 1350 ppm Mg2+, 400 ppm Ca2+, 380 ppm K+, 140 ppm HCO3-, and 65 ppm Br-.
(a) What is the total molality of all ions present in seawater?
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Textbook Question
The van't Hoff factor for CaCl2 is 2.71. What is its mass % in an aqueous solution that has Tf = - 1.14 °C?
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