Ch.13 - Solutions & Their Properties
Chapter 13, Problem 116
A solution of citric acid, C6H8O7, in 50.0 g of acetic acid has a boiling point elevation of ΔT = 1.76 °C. What is the molality of the solution if the molal boilin# g-point-elevation constant for acetic acid is Kb = 3.07 1°C kg2>mol.
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Textbook Question
Cyclopentane 1C5H102 and cyclohexane 1C6H122 are vola- tile, nonpolar hydrocarbons. At 30.0 °C, the vapor pres- sure of cyclopentane is 385 mm Hg, and the vapor pressure of cyclohexane is 122 mm Hg. What is Xpentane in a mixture of C5H10 and C6H12 that has a vapor pressure of 212 mm Hg at 30.0 °C?
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Textbook Question
A solution prepared by dissolving 5.00 g of aspirin, C9H8O4, in 215 g of chloroform has a normal boiling point that is elevated by ΔT = 0.47 °C over that of pure chloro- form. What is the value of the molal boiling-point-elevation constant for chloroform?
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Textbook Question
A solution prepared by dissolving 3.00 g of ascorbic acid (vitamin C, C6H8O6) in 50.0 g of acetic acid has a freez- ing point that is depressed by ΔT = 1.33 °C below that ofpure acetic acid. What is the value of the molal freezing- point-depression constant for acetic acid?
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Textbook Question
What osmotic pressure in mm Hg would you expect for an aqueous solution of 11.5 mg of insulin 1mol. weight = 59902
in 6.60 mL of solution at 298 K? What would the height of the water column be in meters? The density of mercury is
13.534 g/mL at 298 K.
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Textbook Question
Human blood gives rise to an osmotic pressure of approxi-mately 7.7 atm at body temperature, 37.0 °C. What must the molarity of an intravenous glucose solution be to give rise to the same osmotic pressure as blood?
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Textbook Question
13.122 When salt is spread on snow-covered roads at - 2 °C, the snow melts. When salt is spread on snow-covered roads at
- 30 °C, nothing happens. Explain.
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