Ch.12 - Solids and Solid-State Materials
Chapter 12, Problem 72
The melting points for the second-series transition elements increase from 1522 °C for yttrium to 2623 °C for molybdenum and then decrease to 321 °C for cadmium. Account for the trend using band theory.
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Related Practice
Textbook Question
Draw an MO energy-level diagram that shows the population
of the 4s band for potassium metal.
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Textbook Question
State whether each of the following compounds is likely to have a liquid crystalline phase. Explain your reasoning. (a)
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Textbook Question
Draw an MO energy-level diagram for beryllium metal, and
show the population of the MOs for the following two cases.
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Which diagram agrees with the fact that beryllium has a
high electrical conductivity? Explain.
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Textbook Question
Tungsten is hard and has a very high melting point
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electron-sea model or the MO model (band theory)? Explain.
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Explain why the enthalpy of vaporization of vanadium
(460 kJ/mol) is much larger than that of zinc (114 kJ/mol).
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Textbook Question
Tell what is meant by each of the following terms.
(c) Band gap
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