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Ch.7 - Covalent Bonding and Electron-Dot Structures
Chapter 7, Problem 41

Why do two atoms come together to form a covalent bond? (a) Attractive forces between the positively charged nuclei and the electrons in both atoms occur when the atoms are close together. (b) Repulsive forces between protons in the nuclei of the two atoms are minimized when the atoms are close together. (c) Repulsive forces between electrons in the two atoms are minimized when the atoms are close together.

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1
Identify the nature of a covalent bond: A covalent bond involves the sharing of electrons between two atoms.
Consider the forces at play: In a covalent bond, attractive forces between the positively charged nuclei of the atoms and the negatively charged electrons are significant.
Evaluate option (a): Attractive forces between the positively charged nuclei and the electrons in both atoms occur when the atoms are close together. This is a key characteristic of covalent bonding.
Evaluate option (b): Repulsive forces between protons in the nuclei are not minimized; rather, they are balanced by the attractive forces between electrons and nuclei.
Evaluate option (c): Repulsive forces between electrons are not minimized; they are balanced by the attractive forces between electrons and nuclei, allowing the atoms to share electrons effectively.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Covalent Bonding

Covalent bonding occurs when two atoms share one or more pairs of electrons, allowing them to achieve a more stable electron configuration. This type of bond typically forms between nonmetals and is characterized by the overlap of atomic orbitals, leading to the formation of a molecule. The shared electrons create a balance between attractive and repulsive forces, stabilizing the bond.
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Attractive and Repulsive Forces

In atomic interactions, attractive forces arise between the positively charged nuclei of atoms and the negatively charged electrons. Conversely, repulsive forces occur between like charges, such as protons in the nuclei or electrons in the electron clouds. The balance of these forces is crucial in determining the stability of a bond; attractive forces promote bonding, while repulsive forces can hinder it.
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Minimization of Energy

Atoms tend to bond in a way that minimizes their potential energy, leading to a more stable arrangement. When two atoms approach each other, the attractive forces can outweigh the repulsive forces at an optimal distance, resulting in a lower energy state. This energy minimization is a driving force behind the formation of covalent bonds, as atoms seek to achieve stability through electron sharing.
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