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Ch.7 - Covalent Bonding and Electron-Dot Structures
Chapter 7, Problem 35

Characterize bonds between the two atoms as covalent or ionic. (a) Cl and F (b) Rb and F (c) Na and S (d) N and S

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Step 1: Understand the difference between covalent and ionic bonds. Covalent bonds involve the sharing of electrons between atoms, typically nonmetals, while ionic bonds involve the transfer of electrons from one atom to another, typically between a metal and a nonmetal.
Step 2: Analyze the electronegativity difference between the two atoms in each pair. A large difference (usually greater than 1.7) suggests an ionic bond, while a smaller difference suggests a covalent bond.
Step 3: For each pair, identify whether the atoms are metals or nonmetals. Nonmetals tend to form covalent bonds with each other, while metals and nonmetals tend to form ionic bonds.
Step 4: Apply these principles to each pair: (a) Cl and F are both nonmetals, likely forming a covalent bond. (b) Rb is a metal and F is a nonmetal, likely forming an ionic bond. (c) Na is a metal and S is a nonmetal, likely forming an ionic bond. (d) N and S are both nonmetals, likely forming a covalent bond.
Step 5: Conclude by characterizing each bond based on the analysis: (a) covalent, (b) ionic, (c) ionic, (d) covalent.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Covalent Bonds

Covalent bonds form when two atoms share one or more pairs of electrons, typically between nonmetals. This sharing allows each atom to attain a stable electron configuration, often resembling that of noble gases. For example, in a Cl-F bond, both chlorine and fluorine are nonmetals that share electrons, resulting in a covalent bond.
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Ionic Bonds

Ionic bonds occur when one atom donates an electron to another, resulting in the formation of charged ions. This typically happens between metals and nonmetals, where the metal loses electrons and becomes positively charged, while the nonmetal gains electrons and becomes negatively charged. For instance, in the Rb-F bond, rubidium (a metal) donates an electron to fluorine (a nonmetal), creating an ionic bond.
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Electronegativity

Electronegativity is a measure of an atom's ability to attract and hold onto electrons in a bond. The difference in electronegativity between two atoms helps determine the type of bond formed: a large difference typically indicates an ionic bond, while a small difference suggests a covalent bond. For example, the electronegativity difference between Na and S indicates that they will form an ionic bond, while the difference between N and S suggests a covalent bond.
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Related Practice
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The following ball-and-stick molecular model is a representation of thalidomide, a drug that causes birth defects when taken by expectant mothers but is valuable for its use against leprosy. The lines indicate only the connections between atoms, not whether the bonds are single, double, or triple. (Red = O, gray = C, blue = N, ivory = H). Give the formula of thalidomide, and indicate the positions of multiple bonds and lone pairs.

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Match the following descriptions with the type of bond (ionic, nonpolar covalent, covalent). (a) One or more electrons are transferred from a metal to a nonmetal atom.
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