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Ch.22 - The Main Group Elements
Chapter 22, Problem 9

Describe the shape of each of the following molecules or ions, and tell which hybrid orbitals are used by the central atom. (a) GeBr4 (b) CO2 (c) CO32- (d) SnCl3-

Verified step by step guidance
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Step 1: Determine the central atom and count the total number of valence electrons for each molecule or ion. For example, in GeBr4, the central atom is Ge, and you need to consider the valence electrons from Ge and Br atoms.
Step 2: Use the VSEPR (Valence Shell Electron Pair Repulsion) theory to predict the molecular geometry. For GeBr4, with four bonding pairs and no lone pairs on the central atom, the shape is tetrahedral.
Step 3: Identify the hybridization of the central atom based on the number of electron domains (bonding and lone pairs). For GeBr4, with four electron domains, the hybridization is sp3.
Step 4: Repeat the process for CO2. The central atom is C, with two double bonds to O atoms. According to VSEPR, the shape is linear, and the hybridization is sp.
Step 5: For CO32-, consider the resonance structures and the central atom C. With three bonding pairs and no lone pairs, the shape is trigonal planar, and the hybridization is sp2. For SnCl3-, the central atom Sn has three bonding pairs and one lone pair, resulting in a trigonal pyramidal shape with sp3 hybridization.
Related Practice
Open Question
Draw the electron-dot structure for BH3. What are the hybrid orbitals used by boron to form bonds with hydrogen, and will BH3 act as a Lewis acid or a Lewis base? (LO 22.9) (a) sp3; Lewis acid (b) sp3; Lewis base (c) sp2; Lewis acid (d) sp2; Lewis base
Open Question
The silicate anion in the mineral kinoite is represented by the following structure. The mineral also contains Ca2+ ions, Cu2+ ions, and water molecules in a 1:1:1 ratio. What are the formula and charge of the silicate anion, and what is the complete formula for the mineral? (LO 22.11) (a) Si3O10^8-; Ca2Cu2Si3O10 · 2 H2O (b) Si3O8^10-; Ca3Cu2Si3O8 · 2 H2O (c) Si3O4^4-; CaCuSi3O8 · H2O (d) Si3O12^12-; Ca3Cu3Si3O12 · 3 H2O
Open Question
Write chemical equations for the reaction of potassium with the following substances, ensuring that the numbers and kinds of atoms are the same on both sides of the equations. If no reaction occurs, write N.R. (b) Br₂ (c) O₂
Textbook Question

Consider the following oxoacids: HClO, HClO2, HClO3, and HClO4. In which oxoacid does chlorine have an oxidation state of +5? Which oxoacid is the strongest?

(LO 22.17)

(a) HClO has a Cl oxidation state of +5, and HClO4 is the strongest acid.

(b) HClO2 has a Cl oxidation state of +5, and HClO is the strongest acid.

(c) HClO3 has a Cl oxidation state of +5, and HClO4 is the strongest acid.

(d) HClO4 has a Cl oxidation state of +5, and HClO is the strongest acid.

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Open Question
Predict the geometrical structure of each of the following molecules or ions: (a) NO2- (b) PH3 (c) PF5 (d) PCl4+.
Open Question
Write a balanced equation for the reaction of an excess of O2 with each of the following elements: (b) P, (c) Al, (d) Si.