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Ch.2 - Atoms, Molecules & Ions
Chapter 2, Problem 159

What are the charges on the positive ions in the following compounds? (a) Zn(CN)2 (b) Fe(NO2)3 (c) Ti(SO4)2 (d) Sn3(PO4)2 (e) Hg2S (f) MnO2 (g) KIO (h) Cu(CH3CO2)2

Verified step by step guidance
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Step 1: Identify the overall charge of the compound. Since these are neutral compounds, the sum of the charges of the positive and negative ions must equal zero.
Step 2: Determine the charge of the negative ion (anion) in each compound. Use the known charges of common polyatomic ions and monatomic ions. For example, CN^- has a charge of -1, NO2^- has a charge of -1, SO4^2- has a charge of -2, PO4^3- has a charge of -3, S^2- has a charge of -2, O^2- has a charge of -2, IO^- has a charge of -1, and CH3CO2^- has a charge of -1.
Step 3: Calculate the total negative charge in each compound by multiplying the charge of the anion by the number of anions present in the formula. For example, in Zn(CN)2, there are 2 CN^- ions, so the total negative charge is 2(-1) = -2.
Step 4: Determine the charge on the positive ion (cation) by ensuring the total positive charge balances the total negative charge to make the compound neutral. For example, in Zn(CN)2, the total negative charge is -2, so the charge on Zn must be +2 to balance it.
Step 5: Repeat the process for each compound, ensuring the sum of the charges of the cations and anions equals zero for each compound.