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Ch.20 - Nuclear Chemistry
Chapter 20, Problem 92

Can fuel rods in a power plant be used to make an atomic weapon without further treatment? Explain.

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1
Understand the difference between the fuel used in nuclear power plants and the material used in atomic weapons. Nuclear power plants typically use fuel that is enriched to about 3-5% uranium-235, whereas weapons-grade uranium is enriched to about 90% uranium-235.
Recognize that the process of enrichment involves increasing the percentage of uranium-235 in natural uranium. This is achieved through techniques such as gaseous diffusion or gas centrifugation.
Acknowledge that fuel rods from a nuclear reactor contain not only uranium but also a variety of other isotopes, including plutonium, which are produced during the fission process in the reactor.
Consider the technical and legal barriers to using nuclear reactor fuel for weapons. Reprocessing spent nuclear fuel to extract plutonium or further enrich uranium-235 to weapons-grade requires sophisticated technology, stringent safety measures, and is heavily regulated by international agreements to prevent proliferation.
Conclude that while theoretically possible, converting nuclear reactor fuel into weapons-grade material is highly impractical, heavily guarded by international law, and requires advanced technological processes that go beyond simply obtaining spent fuel rods.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Nuclear Fission

Nuclear fission is the process by which a heavy nucleus splits into two or more lighter nuclei, releasing a significant amount of energy. This reaction is the fundamental principle behind both nuclear power generation and atomic weapons. In power plants, controlled fission occurs to produce energy, while in weapons, an uncontrolled chain reaction is desired for explosive yield.
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Enrichment of Uranium

Uranium used in nuclear reactors typically contains a low percentage of the fissile isotope U-235, with the majority being U-238. For atomic weapons, uranium must be enriched to increase the proportion of U-235, making it more suitable for rapid fission. Fuel rods from power plants usually contain low-enriched uranium, which is not sufficient for weaponization without further processing.
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Radioactive Decay and Isotope Stability

Radioactive decay refers to the process by which unstable atomic nuclei lose energy by emitting radiation. The stability of isotopes plays a crucial role in determining their suitability for nuclear reactions. Fuel rods contain isotopes that may decay over time, and the presence of isotopes like plutonium, which can be bred from U-238 in reactors, can complicate the potential for weaponization without additional treatment.
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