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Ch.16 - Aqueous Equilibria: Acids & Bases
Chapter 16, Problem 48

Which of the following are Brønsted–Lowry bases but not Arrhenius bases? (a) NH3 (b) HCO3-

Verified step by step guidance
1
Step 1: Understand the definitions of Brønsted–Lowry and Arrhenius bases. A Brønsted–Lowry base is a substance that can accept a proton (H+), while an Arrhenius base is a substance that increases the concentration of OH- ions in aqueous solution.
Step 2: Analyze NH3 (ammonia). NH3 can accept a proton to form NH4+, making it a Brønsted–Lowry base. However, it does not directly produce OH- ions in solution, so it is not an Arrhenius base.
Step 3: Analyze HCO3- (bicarbonate ion). HCO3- can accept a proton to form H2CO3, making it a Brønsted–Lowry base. It can also react with water to produce OH- ions, so it can act as an Arrhenius base as well.
Step 4: Compare the two substances. NH3 is a Brønsted–Lowry base but not an Arrhenius base, while HCO3- can act as both.
Step 5: Conclude that NH3 is the substance that fits the criteria of being a Brønsted–Lowry base but not an Arrhenius base.