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Ch.15 - Chemical Equilibrium
Chapter 15, Problem 117

Calculate the equilibrium concentrations of H2O(g), Cl2(g), HCl(g), and O2(g) at 298 K if the initial concentrations are [H2O] = 0.050 M and [Cl2] = 0.100 M. The equilibrium constant Kc for the reaction H2O(g) + Cl2(g) ⇌ 2 HCl(g) + O2(g) is 8.96 × 10^-9 at 298 K.

Verified step by step guidance
1
Write the balanced chemical equation for the reaction: H2O(g) + Cl2(g) ⇌ 2 HCl(g) + O2(g).
Set up an ICE (Initial, Change, Equilibrium) table to track the concentrations of each species. Initially, [H2O] = 0.050 M, [Cl2] = 0.100 M, and [HCl] and [O2] are 0 M.
Define the change in concentration for the reactants and products in terms of x, where x is the amount of H2O and Cl2 that reacts. The changes will be: -x for H2O and Cl2, +2x for HCl, and +x for O2.
Express the equilibrium concentrations in terms of x: [H2O] = 0.050 - x, [Cl2] = 0.100 - x, [HCl] = 2x, and [O2] = x.
Substitute these expressions into the equilibrium constant expression Kc = ([HCl]^2[O2])/([H2O][Cl2]) and solve for x using the given Kc value of 8.96 × 10^-9.
Related Practice
Open Question
When 9.25 g of ClF3 was introduced into an empty 2.00-L container at 700.0 K, 19.8% of the ClF3 decomposed to give an equilibrium mixture of ClF3, ClF, and F2. ClF3 (g) ⇌ ClF (g) + F2 (g). (a) What is the value of the equilibrium constant Kc at 700.0 K? (b) What is the value of the equilibrium constant Kp at 700.0 K? (c) In a separate experiment, 39.4 g of ClF3 was introduced into an empty 2.00-L container at 700.0 K. What are the concentrations of ClF3, ClF, and F2 when the mixture reaches equilibrium?
Textbook Question
The reaction of fumarate with water to form L-malate is catalyzed by the enzyme fumarase; Kc = 3.3 at 37°C. When a reaction mixture with [fumarate] = 1.56 * 10-3 M and [l -malate] = 2.27 * 10-3 M comes to equilibrium in the presence of fumarase at 37 °C, what are the equilibrium concentrations of fumarate and L-malate? (Water can be omit- ted from the equilibrium equation because its concentration in dilute solutions is essentially the same as that in pure water.)
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Open Question
Calculate the equilibrium concentrations of SO2, Cl2, and SO2Cl2 at 298 K if the initial concentrations are [SO2] = 1.50 M and [Cl2] = 0.85 M. The equilibrium constant Kc for the reaction SO2(g) + Cl2(g) ⇌ SO2Cl2(g) is 8.40 × 10^-3 at 298 K.
Textbook Question

Consider the following equilibrium: Ag+ (aq) + Cl-(aq) → AgCl(s) Use Le Châtelier's principle to predict how the amount of solid silver chloride will change when the equilibrium is disturbed by: (c) Adding NO3, which reacts with Ag+ to form the complex ion Ag(NH3)2+

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Textbook Question

Consider the following equilibrium: Ag+(aq) + Cl-(aq) ⇌ AgCl(s) Use Le Châtelier's principle to predict how the amount of solid silver chloride will change when the equilibrium is disturbed by: (d) Removing Cl-; also account for the change using the reaction quotient Qc

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Open Question
Will the concentration of NO2 increase, decrease, or remain the same when the equilibrium NO2Cl(g) + NO(g) ⇌ NOCl(g) + NO2(g) is disturbed by the following changes? (a) Adding NOCl (b) Adding NO (c) Removing NO (d) Adding NO2Cl; also account for the change using the reaction quotient Qc