Skip to main content
Ch.18 - Chemistry of the Environment

Chapter 18, Problem 56

In the following three instances, which choice is greener in a chemical process? Explain. (a) A reaction that can be run at 350 K for 12 h without a catalyst or one that can be run at 300 K for 1 h with a reusable catalyst.

Verified Solution
Video duration:
1m
This video solution was recommended by our tutors as helpful for the problem above.
379
views
Was this helpful?

Video transcript

Hi everyone for this problem, we are asked which of the following reactions is a greener chemical process. So, essentially, here we're being asked which one is a safer chemical process. So, let's take a look. A methanol is used as a solvent for the reaction. The reaction reaches completion after eight hours without the catalyst or be water is used as a solvent for the reaction. The reaction reaches completion after one hour with a catalyst. So here we're comparing methanol to water and we also have a time frame associated with both. For methanol, it reaches completion after eight hours and without a catalyst. And for option B it reaches completion after one hour with a catalyst. So, which one of these is a greener chemical process. So, if we take a look, water is the safer solvent because it's non toxic to the environment compared to methanol. It's also the faster reaction out of the two given here. So it's undergoing catalysis because it says with a catalyst. So, because it's undergoing catalysis, it's faster and has a lower energy requirement. So, in terms of a greener chemical process, answer Choice B is going to be our greener chemical process. Okay, so that's the answer to this problem. And that's the end of this problem. I hope this was helpful
Related Practice
Textbook Question

In the lime soda process once used in large scale munici-pal water softening, calcium hydroxide prepared from lime and sodium carbonate are added to precipitate Ca2+ as CaCO3(s) and Mg2+ as Mg(OH)2(s): Ca2+(aq) + CO32-(aq) → CaCO3(s) Mg2+(aq) + 2 OH-(aq) → MgOH2(aq) How many moles of Ca(OH)2 and Na2CO3 should be added to soften (remove the Ca2+ and Mg2+) 1200 L of water in which [Ca2+] = 5.0x10-4 M and [Mg2+] = 7.0x10-4 M?

852
views
Textbook Question

(b) Draw the Lewis structures of two example THMs.

739
views
Textbook Question

A reaction for converting ketones to lactones, called the Baeyer–Villiger reaction,

is used in the manufacture of plastics and pharmaceu- ticals. 3-Chloroperbenzoic acid is shock-sensitive, how- ever, and prone to explode. Also, 3-chlorobenzoic acid is a waste product. An alternative process being developed uses hydrogen peroxide and a catalyst consisting of tin deposited within a solid support. The catalyst is readily recovered from the reaction mixture. (a) What would you expect to be the other product of oxidation of the ketone to lactone by hydrogen peroxide?

727
views
Textbook Question

(a) What is the difference between a CFC and an HFC?

127
views
Textbook Question

Natural gas consists primarily of methane, CH4(g). (b) Write a balanced chemical equation for the incomplete combustion of methane to product CO(g) as the only carbon-containg product.

617
views