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Ch.23 - Transition Metals and Coordination Chemistry
Chapter 23, Problem 15b

Write out the ground-state electron configurations of b. Ru²⁺

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Identify the atomic number of Ruthenium (Ru) from the periodic table. The atomic number tells you the number of protons and, in a neutral atom, the number of electrons.
Write the electron configuration for a neutral Ruthenium atom. Ruthenium is in the 4d block of the periodic table, so its electrons will fill the 4d orbital after the 4s and 4p orbitals.
Remove electrons to account for the 2+ charge of Ru²⁺. Electrons are removed from the outermost orbitals first, typically starting from the highest energy level orbital.
Rearrange the remaining electrons to reflect the electron configuration of Ru²⁺, ensuring that the orbitals are filled according to Hund's Rule (maximum multiplicity) and the Pauli Exclusion Principle (no two electrons in the same atom can have the same four quantum numbers).
Verify the electron configuration by ensuring the total number of electrons equals the atomic number of Ruthenium minus the charge (44 - 2 = 42 electrons).

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electron Configuration

Electron configuration describes the distribution of electrons in an atom's orbitals. It follows the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level to the highest. The notation typically includes the principal quantum number, the type of orbital, and the number of electrons in that orbital, such as 1s² 2s² 2p⁶.
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Transition Metals

Transition metals are elements found in the d-block of the periodic table, characterized by their ability to form variable oxidation states and colored compounds. They have partially filled d orbitals, which play a crucial role in their chemical properties and electron configurations. Understanding their electron configurations is essential for predicting their behavior in chemical reactions.
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Oxidation States

Oxidation states indicate the degree of oxidation of an atom in a compound, reflecting the number of electrons lost, gained, or shared. For example, in the case of Ru²⁺, the oxidation state of +2 means that the ruthenium atom has lost two electrons compared to its neutral state. This change affects its electron configuration, as electrons are removed from the highest energy orbitals.
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Related Practice
Textbook Question

Four-coordinate metals can have either a tetrahedral or a square-planar geometry; both possibilities are shown here for [PtCl2(NH3)2].

a. What is the name of this molecule?

b. Would the tetrahedral molecule have a geometric isomer?

c. Would the tetrahedral molecule be diamagnetic or paramagnetic?

d. Would the square-planar molecule have a geometric isomer?

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Textbook Question

Which of these crystal-field splitting diagrams represents:

a. a weak-field octahedral complex of Fe³⁺ ,

b. a strong-field octahedral complex of Fe³⁺ 

c. a tetrahedral complex of Fe³⁺

d. a tetrahedral complex of Ni²⁺ (The diagrams do not indicate the relative magnitudes of ∆. ) [Find more in Section 23.6.]

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Textbook Question

In the linear crystal-field shown here, the negative charges are on the z-axis. Using Figure 23.28 as a guide, predict which of the following choices most accurately describes the splitting of the d orbitals in a linear crystal-field? [Find more in Section 23.6.]                                                                                                                                                

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Textbook Question

Write out the ground-state electron configurations of  c. Au³⁺ ,

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Textbook Question

Which type of substance is attracted by a magnetic field, a diamagnetic substance or a paramagnetic substance?

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Textbook Question

The lobes of which d orbitals point directly between the ligands in a. octahedral geometry,

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