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Ch.20 - Electrochemistry
Chapter 20, Problem 109

Calculate the number of kilowatt-hours of electricity required to produce 1.0 * 103 kg (1 metric ton) of aluminum by electrolysis of Al3+ if the applied voltage is 4.50 V and the process is 45% efficient.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electrolysis

Electrolysis is a chemical process that uses electrical energy to drive a non-spontaneous reaction. In the case of aluminum production, an electric current is passed through a molten aluminum oxide solution, causing the Al3+ ions to gain electrons and form aluminum metal. Understanding the principles of electrolysis, including Faraday's laws, is essential for calculating the energy requirements for the process.
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Efficiency

Efficiency in a chemical process refers to the ratio of useful output to the total input, often expressed as a percentage. In this context, the 45% efficiency indicates that only 45% of the electrical energy supplied is effectively used for the electrolysis of aluminum. This concept is crucial for determining the actual energy consumption needed to produce the desired amount of aluminum.
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Kilowatt-Hour (kWh)

A kilowatt-hour (kWh) is a unit of energy equivalent to one kilowatt (1 kW) of power used for one hour. It is commonly used to measure electrical energy consumption. In this problem, calculating the total kWh required involves converting the energy needed for the electrolysis process into this unit, taking into account the voltage applied and the efficiency of the process.
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Related Practice
Textbook Question

The capacity of batteries such as the typical AA alkaline battery is expressed in units of milliamp-hours (mAh). An AA alkaline battery yields a nominal capacity of 2850 mAh. (b) The starting voltage of a fresh alkaline battery is 1.55 V. The voltage decreases during discharge and is 0.80 V when the battery has delivered its rated capacity. If we assume that the voltage declines linearly as current is withdrawn, estimate the total maximum electrical work the battery could perform during discharge.

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Textbook Question

Disulfides are compounds that have S ¬ S bonds, like peroxides have O ¬ O bonds. Thiols are organic compounds that have the general formula R ¬ SH, where R is a generic hydrocarbon. The SH- ion is the sulfur counterpart of hydroxide, OH-. Two thiols can react to make a disulfide, R ¬ S ¬ S ¬ R. (b) What is the oxidation state of sulfur in a disulfide?

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Textbook Question

Disulfides are compounds that have S ¬ S bonds, like peroxides have O ¬ O bonds. Thiols are organic compounds that have the general formula R ¬ SH, where R is a generic hydrocarbon. The SH- ion is the sulfur counterpart of hydroxide, OH-. Two thiols can react to make a disulfide, R ¬ S ¬ S ¬ R. (c) If you react two thiols to make a disulfide, are you oxidizing or reducing the thiols?

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Textbook Question

Aqueous solutions of ammonia 1NH32 and bleach (active ingredient NaOCl) are sold as cleaning fluids, but bottles of both of them warn: 'Never mix ammonia and bleach, as toxic gases may be produced.' One of the toxic gases that can be produced is chloroamine, NH2Cl. (b) What is the oxidation number of chlorine in chloramine?

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Textbook Question

Aqueous solutions of ammonia 1NH32 and bleach (active ingredient NaOCl) are sold as cleaning fluids, but bottles of both of them warn: 'Never mix ammonia and bleach, as toxic gases may be produced.' One of the toxic gases that can be produced is chloroamine, NH2Cl. (e) Is N oxidized, reduced, or neither, upon the conversion of ammonia to nitrogen trichloride?

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Textbook Question

Cytochrome, a complicated molecule that we will represent as CyFe2+, reacts with the air we breathe to supply energy required to synthesize adenosine triphosphate (ATP). The body uses ATP as an energy source to drive other reactions (Section 19.7). At pH 7.0 the following reduction potentials pertain to this oxidation of CyFe2+: O21g2 + 4 H+1aq2 + 4 e- ¡ 2 H2O1l2 Ered ° = +0.82 V CyFe3+1aq2 + e- ¡ CyFe2+1aq2 E°red = +0.22 V (a) What is ∆G for the oxidation of CyFe2+ by air? (b) If the synthesis of 1.00 mol of ATP from adenosine diphosphate (ADP) requires a ∆G of 37.7 kJ, how many moles of ATP are synthesized per mole of O2?

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