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Ch.19 - Chemical Thermodynamics

Chapter 19, Problem 26b

(b) In a particular spontaneous process the entropy of the system decreases. What can you conclude about the sign and magnitude of ΔSsurr?

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Hello. In this problem we are told for non spontaneous process, the change in entropy of the system is negative whereas to identify the sign for the change in entropy of the universe. So the change in HP of the universe is equal to the change in entropy of the system. Plus the change in entropy of the surroundings. If we have a non spontaneous process and the change in entropy of the universe will be negative. We have a spontaneous process. The change in entropy of the universe will be positive. And if we have a reversible process the change in entropy of the universe will be equal to zero. So given that we have a non spontaneous process, that means then the sign for the change in entropy of the universe is going to be negative. And this corresponds to answer C. Thanks for watching. Hope. This helps
Related Practice
Textbook Question

The element gallium (Ga) freezes at 29.8 °C, and its molar enthalpy of fusion is ΔHfus = 5.59 kJ/mol. (b) Calculate the value of ΔS when 60.0 g of Ga(l) solidifies at 29.8 °C.

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Textbook Question

Indicate whether each statement is true or false. (c) In a certain spontaneous process the system undergoes an entropy change of 4.2 J/K; therefore, the entropy change of the surroundings must be -4.2 J/K.

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Textbook Question

(a) Does the entropy of the surroundings increase for spontaneous processes?

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Textbook Question

(c) During a certain reversible process, the surroundings undergo an entropy change, ΔSsurr = -78 J/K. What is the entropy change of the system for this process?

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Textbook Question

(a) What sign for Δ𝑆 do you expect when the pressure on 0.600 mol of an ideal gas at 350 K is increased isothermally from an initial pressure of 0.750 atm?

(b) If the final pressure on the gas is 1.20 atm, calculate the entropy change for the process.

(c) Which of the following statements about this process are true? (i) The entropy change you calculated will be the same for at any other constant temperature. (ii) The value of Δ𝑆 you calculated is valid only if the compression is done irreversibly. (iii) If the number of moles of gas being compressed were decreased by a factor of three, the entropy change would increase by a factor of three.

Textbook Question

For the isothermal expansion of a gas into a vacuum, ΔE = 0, q = 0, and w = 0. (b) Explain why no work is done by the system during this process.

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