Write a chemical equation that illustrates the autoionization of water.
Ch.16 - Acid-Base Equilibria
Chapter 16, Problem 34a
Calculate 3OH-4 for each of the following solutions, and indicate whether the solution is acidic, basic, or neutral: (a) 3H+4 = 0.0505 M

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Identify the given concentration: \([H^+] = 0.0505\, \text{M}\).
Use the relationship between \([H^+]\) and \([OH^-]\) in water: \([H^+][OH^-] = 1.0 \times 10^{-14}\, \text{at 25°C}\).
Rearrange the equation to solve for \([OH^-]\): \([OH^-] = \frac{1.0 \times 10^{-14}}{[H^+]}\).
Substitute the given \([H^+]\) value into the equation: \([OH^-] = \frac{1.0 \times 10^{-14}}{0.0505}\, \text{M}\).
Determine if the solution is acidic, basic, or neutral by comparing \([H^+]\) and \([OH^-]\): If \([H^+] > [OH^-]\), the solution is acidic; if \([H^+] < [OH^-]\), it is basic; if \([H^+] = [OH^-]\), it is neutral.

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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
pH and pOH
pH is a measure of the hydrogen ion concentration in a solution, indicating its acidity or basicity. The pOH is similarly a measure of hydroxide ion concentration. The relationship between pH and pOH is defined by the equation pH + pOH = 14 at 25°C. Understanding these concepts is essential for determining the nature of a solution.
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Acidic, Basic, and Neutral Solutions
A solution is considered acidic if its pH is less than 7, basic if its pH is greater than 7, and neutral if its pH is exactly 7. The concentration of hydrogen ions (H+) and hydroxide ions (OH-) in a solution determines its classification. For example, a higher concentration of H+ indicates acidity, while a higher concentration of OH- indicates basicity.
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Calculating pOH from pH
To find the pOH from a given concentration of H+, one first calculates the pH using the formula pH = -log[H+]. Once the pH is determined, pOH can be calculated using the relationship pOH = 14 - pH. This calculation is crucial for determining the hydroxide ion concentration and the overall nature of the solution.
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Related Practice
Textbook Question
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Write the expression for the ion product constant for water, Kw.
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Calculate 3OH-4 for each of the following solutions, and indicate whether the solution is acidic, basic, or neutral: (b) 3H+4 = 2.5 * 10-10 M
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Calculate 3OH-4 for each of the following solutions, and indicate whether the solution is acidic, basic, or neutral: (c) a solution in which 3H+4 is 1000 times greater than 3OH-4.
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Textbook Question
Deuterium oxide 1D2O, where D is deuterium, the hydrogen-2 isotope) has an ion-product constant, Kw, of 8.9 * 10-16 at 20 °C. Calculate 3D+4 and 3OD-4 for pure (neutral) D2O at this temperature.
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