Chapter 15, Problem 10a
The diagram shown here represents the equilibrium state for the reaction A2(π) + 2B(π) β 2AB(π). (a) Assuming the volume is 2 L, calculate the equilibrium constant πΎπ for the reaction.
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When lead(IV) oxide is heated above 300Β°C, it decomposes according to the reaction, 2 PbO2(π )β2PbO(π )+O2(π). Consider the two sealed vessels of PbO2 shown here. If both vessels are heated to 400Β°C and allowed to come to equilibrium, which of the following statements is or are true?
b. The solid left at the bottom of each vessel will be a mixture of PbO2(π ) and PbO(π ).
When lead(IV) oxide is heated above 300Β°C, it decomposes according to the reaction, 2 PbO2(π )β2PbO(π )+O2(π). Consider the two sealed vessels of PbO2 shown here. If both vessels are heated to 400Β°C and allowed to come to equilibrium, which of the following statements is or are true? c. The partial pressure of O2(π) will be the same in vessels A and B. [Section 15.4]
The reaction A2 + B2 β 2 AB has an equilibrium constant Kc = 1.5. The following diagrams represent reaction mixtures containing A2 molecules (red), B2 molecules (blue), and AB molecules. (a) Which reaction mixture is at equilibrium?
Suppose that the gas-phase reactions A β B and B β A are both elementary reactions with rate constants of 4.7Γ10β3β sβ1 and 5.8Γ10β1 sβ1, respectively. (b) Which is greater at equilibrium, the partial pressure of A or the partial pressure of B?
The equilibrium constant for the dissociation of molecular iodine, I2(π) β 2 I(π), at 800 K is πΎπ = 3.1Γ10β5. (b) Assuming both forward and reverse reactions are elementary reactions, which reaction has the larger rate constant, the forward or the reverse reaction?
Write the expression for πΎπ for the following reactions. In each case indicate whether the reaction is homogeneous or heterogeneous.
(e) 2Ag(π ) + Zn2+(ππ) β 2 Ag+(ππ) + Zn(π )