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Ch.14 - Chemical Kinetics

Chapter 14, Problem 41a

(a) The gas-phase decomposition of SO2Cl2, SO2Cl21g2 ¡SO21g2 + Cl21g2, is first order in SO2Cl2. At 600 K the half-life for this process is 2.3 * 105 s. What is the rate constant at this temperature?

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Hello everyone. Today, we have the following problem. The thermal cracking of ethane is a first order process and has a half life of 2.11 times 10 to the negative second seconds at 900 degrees Celsius, determine the rate constant at 900 degrees Celsius. So first, what we wanna do is you wanna draw the equation for half life. The equation for half life is going to be the natural log of two divided by some constant K. And so what we wanna do is they want to rearrange this equation. And so that we're solving for K in that K is going to be equal to the natural log of two divided by our half life simply plugging in the values that we have from the problem. We have the natural log if two can be divided by the half life, which was given to us in the question stem as 2.11 times 10 to the negative second seconds. When we plug this into our calculator, this is going to give us a rate constant of 32.9 seconds raised to the -1. And with that, we have the answer to our problem overall, I hope this helped and until next time.
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Consider the gas-phase reaction between nitric oxide and bromine at 273 C: 2 NO1g2 + Br21g2¡2 NOBr1g2. The following data for the initial rate of appearance of NOBr were obtained: Experiment 3no4 1M 2 3br2 4 1M 2 Initial Rate 1M,s2 1 0.10 0.20 24 2 0.25 0.20 150 3 0.10 0.50 60 4 0.35 0.50 735 (b) Calculate the average value of the rate constant for the appearance of NOBr from the four data sets.

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The first-order rate constant for the decomposition of N2O5, 2 N2O51g2¡4 NO21g2 + O21g2, a t 70 C i s 6.82 * 10-3 s-1. Suppose we start with 0.0250 mol of N2O51g2 in a volume of 2.0 L. (a) How many moles of N2O5 will remain after 5.0 min?

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The first-order rate constant for the decomposition of N2O5, 2 N2O51g2¡4 NO21g2 + O21g2, a t 70 C i s 6.82 * 10-3 s-1. Suppose we start with 0.0250 mol of N2O51g2 in a volume of 2.0 L. (c) What is the half-life of N2O5 at 70 C ?

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