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Ch.11 - Liquids and Intermolecular Forces
Chapter 11, Problem 64b

Use the phase diagram of neon to answer the following questions. (b) What can you say about the strength of the intermolecular forces in neon and argon based on the critical points of Ne and Ar (see Table 11.5.)?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Phase Diagram

A phase diagram is a graphical representation that shows the phases of a substance at various temperatures and pressures. It delineates the boundaries between different states of matter (solid, liquid, gas) and indicates critical points where phase transitions occur. Understanding phase diagrams is essential for analyzing the behavior of substances under varying conditions.
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Intermolecular Forces

Intermolecular forces are the attractive forces between molecules that influence their physical properties, such as boiling and melting points. These forces include van der Waals forces, dipole-dipole interactions, and hydrogen bonding. The strength of these forces can be inferred from the critical points of substances, as stronger intermolecular forces typically lead to higher critical temperatures and pressures.
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Critical Point

The critical point of a substance is the temperature and pressure at which the distinction between liquid and gas phases disappears, resulting in a supercritical fluid. At this point, the properties of the liquid and gas phases converge, and the substance can no longer exist as a distinct liquid or gas. Analyzing the critical points of neon and argon helps in comparing their intermolecular forces, as substances with higher critical points generally exhibit stronger intermolecular interactions.
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Related Practice
Textbook Question

Appendix B lists the vapor pressure of water at various external pressures. (c) A city at an altitude of 5000 ft above sea level has a barometric pressure of 633 torr. To what temperature would you have to heat water to boil it in this city?

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Textbook Question

Referring to Figure 11.29, describe the phase changes (and the temperatures at which they occur) when CO2 is heated from -80 to -20°C at (a) a constant pressure of 3 atm,

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Textbook Question

The phase diagram for neon is

Use the phase diagram to answer the following questions. (a) What is the approximate value of the normal melting point?

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Textbook Question

At 25°C gallium is a solid with a density of 5.91 g/cm3 and a melting point, 29.8°C, just slightly above room temperature. The density of liquid gallium just above the melting point is 6.1 g/cm3. Based on this information, what unusual feature would you expect to find in the phase diagram of gallium?

Textbook Question

Indicate whether each statement is true or false: (c) Molecules that exhibit a liquid crystalline phase do so at well-defined temperatures and pressures.

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Textbook Question

In all four liquid crystalline phases shown in Figure 11.32, the long axis of the molecule preferentially orders along one or more specific directions. In three of the four phases the molecules also lose some freedom of translational motion. In which of the four liquid crystalline phases do the molecules retain the freedom to move in all three directions that they possess in the liquid phase: nematic, smectic A, smectic C, or cholesteric?