Chapter 11, Problem 37b
Liquids can interact with flat surfaces just as they can with capillary tubes; the cohesive forces within the liquid can be stronger or weaker than the adhesive forces between liquid and surface:
(b) Which of these diagrams, i or ii, rep- resents what happens when water is on a nonpolar surface?
Video transcript
The generic structural formula for a 1-alkyl-3-methylimid- azolium cation is where R is a -CH2(CH2)nCH3 alkyl group. The melting points of the salts that form between 1-alkyl-3-methylimidazolium cation and the PF6- anion are as follows: R = CH2CH3 (m.p. = 60 °C), R = CH2CH2CH3 (m.p. = 40 °C), r = CH2CH2CH2CH3 (m.p. = 10 °C), and R = CH2CH2CH2CH2CH2CH3 (m.p. = -61 °C). Why does the melting point decrease as the length of alkyl group increases?
(b) What is the relationship between viscosity and temperature?
Based on their composition and structure, list CH2Cl2, CH3CH2CH3, and CH3CH2OH in order of (c) increasing surface tension
The boiling points, surface tensions, and viscosities of water and several alcohols are listed in the following table:
b. How do you explain the fact that propanol and ethylene glycol have similar molecular weights (60 vs. 62 amu), yet the viscosity of ethylene glycol is more than 10 times larger than propanol?
Name the phase transition in each of the following situations and indicate whether it is exothermic or endothermic: (c) Rubbing alcohol in an open container slowly disappears.
Name the phase transition in each of the following situations and indicate whether it is exothermic or endothermic: (d) Molten lava from a volcano turns into solid rock.