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Ch.10 - Gases
Chapter 10, Problem 48

Rank the following gases from least dense to most dense at 1.00 atm and 298 K: SO2,HBr,CO2.

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Identify the formula for density of a gas: \( \text{Density} = \frac{\text{Molar Mass}}{\text{Molar Volume}} \). At standard conditions, the molar volume is 22.4 L/mol.
Calculate the molar mass of each gas: \( \text{SO}_2 \), \( \text{HBr} \), and \( \text{CO}_2 \).
For \( \text{SO}_2 \): Add the atomic masses of sulfur (S) and oxygen (O) from the periodic table: \( \text{Molar Mass of SO}_2 = 32.07 + 2 \times 16.00 \).
For \( \text{HBr} \): Add the atomic masses of hydrogen (H) and bromine (Br): \( \text{Molar Mass of HBr} = 1.01 + 79.90 \).
For \( \text{CO}_2 \): Add the atomic masses of carbon (C) and oxygen (O): \( \text{Molar Mass of CO}_2 = 12.01 + 2 \times 16.00 \).

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Density of Gases

The density of a gas is defined as its mass per unit volume, typically expressed in grams per liter (g/L). It is influenced by the gas's molar mass and the conditions of temperature and pressure. At a constant temperature and pressure, gases with higher molar masses will generally have higher densities.
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Ideal Gas Law

The Ideal Gas Law, represented as PV = nRT, relates the pressure (P), volume (V), number of moles (n), gas constant (R), and temperature (T) of an ideal gas. This law helps in understanding how gases behave under different conditions and can be used to derive relationships that affect density, such as the relationship between molar mass and density.
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Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is a critical factor in determining the density of gases; substances with higher molar masses will generally be denser than those with lower molar masses when compared under the same conditions of temperature and pressure.
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Related Practice
Textbook Question

In an experiment reported in the scientific literature, male cockroaches were made to run at different speeds on a miniature treadmill while their oxygen consumption was measured. In 1 h the average cockroach running at 0.08 km/h consumed 0.8 mL of O2 at 1 atm pressure and 24°C per gram of insect mass. a. How many moles of O2 would be consumed in 1 h by a 5.2-g cockroach moving at this speed?

Textbook Question

The physical fitness of athletes is measured by 'VO2 max,' which is the maximum volume of oxygen consumed by an individual during incremental exercise (for example, on a treadmill). An average male has a VO2 max of 45 mL O2/kg body mass/min, but a world-class male athlete can have a VO2 max reading of 88.0 mL O2/kg body mass/min. (a) Calculate the volume of oxygen, in mL, consumed in 1 hr by an average man who weighs 85 kg and has a VO2 max reading of 47.5 mL O2/kg body mass/min.

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Textbook Question

Rank the following gases from least dense to most dense at 1.00 atm and 298 K: CO, N2O, Cl2, HF.

Textbook Question

Which of the following statements best explains why a closed balloon filled with helium gas rises in air? (a) Helium is a monatomic gas, whereas nearly all the molecules that make up air, such as nitrogen and oxygen, are diatomic. (b) The average speed of helium atoms is greater than the average speed of air molecules, and the greater speed of collisions with the balloon walls propels the balloon upward. (c) Because the helium atoms are of lower mass than the average air molecule, the helium gas is less dense than air. The mass of the balloon is thus less than the mass of the air displaced by its volume. (d) Because helium has a lower molar mass than the average air molecule, the helium atoms are in faster motion. This means that the temperature of the helium is greater than the air temperature. Hot gases tend to rise.

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Textbook Question

(a) Calculate the density of NO2 gas at 0.970 atm and 35 °C.

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Textbook Question

(b) Calculate the molar mass of a gas if 2.50 g occupies 0.875 L at 685 torr and 35 °C

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