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Ch.18 - Chemistry of the Environment
Chapter 18, Problem 39a

The enthalpy of evaporation of water is 40.67 kJ/mol. Sunlight striking Earth's surface supplies 168 W per square meter (1 W = 1 watt = 1 J/s). (a) Assuming that evaporation of water is due only to energy input from the Sun, calculate how many grams of water could be evaporated from a 1.00 square meter patch of ocean over a 12-h day

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Enthalpy of Evaporation

The enthalpy of evaporation, or heat of vaporization, is the amount of energy required to convert a unit mass of a liquid into vapor without a change in temperature. For water, this value is 40.67 kJ/mol, indicating that this amount of energy is needed to evaporate one mole of water. Understanding this concept is crucial for calculating how much water can be evaporated given a specific energy input.
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Power and Energy Conversion

Power is the rate at which energy is transferred or converted, measured in watts (W), where 1 W equals 1 joule per second (J/s). In this context, sunlight provides energy at a rate of 168 W per square meter. To find the total energy available over a period, one must multiply the power by the time duration, converting hours into seconds for accurate calculations.
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Mass-Energy Relationship

The mass-energy relationship in chemistry allows us to relate the energy absorbed during a phase change to the mass of the substance undergoing that change. By using the enthalpy of evaporation, we can determine how many grams of water can be evaporated by dividing the total energy available (calculated from power and time) by the energy required to evaporate a specific mass of water. This relationship is fundamental for solving the problem presented.
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Related Practice
Textbook Question

An important reaction in the formation of photochemical smog is the photodissociation of NO : NO2 + hv → NO(g) + O(g) The maximum wavelength of light that can cause this reac- tion is 420 nm. (a) In what part of the electromagnetic spec- trum is light with this wavelength found?

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Textbook Question

What is the molarity of Na+ in a solution of NaCl whose salinity is 5.6 if the solution has a density of 1.03 g>mL?

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Textbook Question

Phosphorus is present in seawater to the extent of 0.07 ppm by mass. Assuming that the phosphorus is present as dihydrogenphosphate, H2PO4-, calculate the correspond-ing molar concentration of H2PO4- in seawater.

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Textbook Question

The enthalpy of fusion of water is 6.01 kJ/mol. Sunlight striking Earth's surface supplies 168 W per square meter (1 W = 1 watt = 1 J/s). (b) The specific heat capacity of ice is 2.032 J/g°C. If the initial temperature of a 1.00 square emter patch of ice is -5.0°C, what is its final temperature after being in sunlight for 12 h, assuming no phase changes and assuming that sunlight penetration uniformly to a depth of 1.00 cm?

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Textbook Question

The Ogallala aquifer described in the Closer Look box in Section 18.3, provides 82% of the drinking water for the people who live in the region, although more than 75% of the water that is pumped from it is for irrigation. Irrigation withdrawals are approximately 18 billion gallons per day. (a) Assuming that 2% of the rainfall that falls on an area of 600,000 km2 recharges the aquifer, what average annual rainfall would be required to replace the water removed for irrigation?

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Textbook Question

The Ogallala aquifer described in the Closer Look box in Section 18.3, provides 82% of the drinking water for the people who live in the region, although more than 75% of the water that is pumped from it is for irrigation. Irrigation withdrawals are approximately 18 billion gallons per day. (b) What process or processes accounts for the presence of arsenic in well water?

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