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Ch.9 - Molecular Geometry and Bonding Theories
Chapter 9, Problem 6b

The orbital diagram that follows presents the final step in the formation of hybrid orbitals by a silicon atom. (b) What type of hybrid orbital is produced in this hybridization?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Hybridization

Hybridization is a concept in chemistry that describes the mixing of atomic orbitals to form new hybrid orbitals. These hybrid orbitals have different energies and shapes compared to the original atomic orbitals, allowing for the formation of more stable molecular structures. In the case of silicon, hybridization typically involves the combination of its 3s and 3p orbitals.
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Types of Hybrid Orbitals

There are several types of hybrid orbitals, including sp, sp2, and sp3, which correspond to the number of atomic orbitals mixed. For example, sp hybridization involves one s and one p orbital, resulting in two equivalent sp orbitals, while sp3 hybridization involves one s and three p orbitals, resulting in four equivalent sp3 orbitals. The type of hybridization affects the geometry and bonding properties of the molecule.
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Silicon's Hybridization

Silicon typically undergoes sp3 hybridization when forming four equivalent bonds, as seen in compounds like silicon tetrafluoride (SiF4). In this process, one 3s and three 3p orbitals combine to create four sp3 hybrid orbitals, which are oriented tetrahedrally. Understanding this hybridization is crucial for predicting the molecular geometry and reactivity of silicon-containing compounds.
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