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Ch.9 - Molecular Geometry and Bonding Theories

Chapter 9, Problem 96a

a) Predict the electron-domain geometry around the central S atom in SF2, SF4, and SF6.

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Hi everyone here we have a three part question. So we're gonna start with a what is the electron domain geometry around selenium and selenium di chloride. So let's draw out our Lewis structure here. We have selenium in the middle With two long pairs And it is bonded to two chlorine each with three lone pairs. So there are four electron groups around selenium, meaning it is an A. X. Four molecule giving it a tetra. He'd real electron domain geometry. Next we have b what is the electron domain geometry around selenium in selenium tetrachloride. So we have selenium in the middle again and it will have one lone pair And then it will be single bonded to four chlorine Each with three long pairs. So it has five electron groups around selenium Making it an X. five molecule and giving it a Trigon all by cram it'll electron geometry. So our answer is for the first two are tetra he'd rel and Trigano by parameter. And now let's look at see what is the electron domain geometry around selenium and selenium hexafluoride. So we're again going to draw the electron geometry. So we're going to have our selenium in the middle surrounded by six chlorine each with three long pairs. So it has six electron groups around selenium Making it an AX six molecule and giving it an Octa he drel electron domain geometry. And that is our last answer. Thank you for watching. Bye
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An AB5 molecule adopts the geometry shown here. (b) Do you think there are any nonbonding electron pairs on atom A?

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An AB5 molecule adopts the geometry shown here. (c) Suppose the B atoms are halogen atoms. Of which group in the periodic table is atom A a member: (i) Group 15, (ii) Group 16, (iii) Group 17, (iv) Group 18, or (v) More information is needed?

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The O¬H bond lengths in the water molecule 1H2O2 are 96 pm, and the H¬O¬H angle is 104.5°. The dipole moment of the water molecule is 1.85 D. (b) Calculate the magnitude of the bond dipole of the O¬H bonds. (Note: You will need to use vector addition to do this.)

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Which of the following statements about hybrid orbitals is or are true? (i) After an atom undergoes sp hybridization, there is one unhybridized p orbital on the atom, (ii) Under sp2 hybridization, the large lobes point to the vertices of an equilateral triangle, and (iii) The angle between the large lobes of sp3 hybrids is 109.5°.

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Sodium azide is a shock-sensitive compound that releases N2 upon physical impact. The compound is used in automobile airbags. The azide ion is N3-. (a) Draw the Lewis structure of the azide ion that minimizes formal charge (it does not form a triangle). Is it linear or bent?

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Textbook Question

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