(a) Based on the lattice energies of MgCl2 and SrCl2 given in Table 8.1, what is the range of values that you would expect for the lattice energy of CaCl2?
Ch.8 - Basic Concepts of Chemical Bonding
Chapter 8, Problem 33e
Using Lewis symbols and Lewis structures, make a sketch of the formation of NCl3 from N and Cl atoms, showing valence-shell electrons. (e) How many lone pairs of electrons are in the NCl3 molecule?
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Lewis Symbols
Lewis symbols represent the valence electrons of an atom as dots surrounding the element's symbol. Each dot corresponds to a valence electron, allowing for a visual representation of how atoms bond and share electrons. This concept is fundamental in predicting how atoms will interact in chemical reactions, particularly in covalent bonding.
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Lewis Structures
Lewis structures are diagrams that depict the arrangement of atoms and the distribution of valence electrons in a molecule. They illustrate how atoms are bonded together and show lone pairs of electrons that are not involved in bonding. Understanding Lewis structures is essential for visualizing molecular geometry and predicting the properties of compounds.
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Lewis Dot Structures: Ions
Lone Pairs
Lone pairs are pairs of valence electrons that are not shared with another atom and are localized on a single atom. In the context of molecular structures, lone pairs can influence the shape and reactivity of a molecule. For NCl3, recognizing the number of lone pairs on the nitrogen atom is crucial for understanding its molecular geometry and overall stability.
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Related Practice
Textbook Question
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Textbook Question
(b) Using data from Appendix C, Figure 7.11, Figure 7.13, and the value of the second ionization energy for Ca, 1145 kJ/mol, calculate the lattice energy of CaCl2.
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Textbook Question
(b) A substance, XY, formed from two different elements, melts at −33 °C. Is XY likely to be a covalent or an ionic substance?
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Textbook Question
Using Lewis symbols and Lewis structures, diagram the formation of PF3 from P and F atoms, showing valence-shell electrons. (c) How many valence electrons surround the P in the PF3 molecule?
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Textbook Question
Using Lewis symbols and Lewis structures, diagram the formation of PF3 from P and F atoms, showing valence-shell electrons. (e) Does PF3 obey the octet rule?
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Textbook Question
(b) How many bonding electrons are in the structure?
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