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Ch.8 - Basic Concepts of Chemical Bonding

Chapter 8, Problem 95

Consider the hypothetical molecule B-A=B. Are the following statements true or false? (a) This molecule cannot exist. (b) If resonance was important, the molecule would have identical A–B bond lengths.

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Hi everyone here we have a question telling us to consider the linear tetra iodide ion and ion I for negative, identify the following statements about this ion as true or false. A This ion does not exist in reality this is true. The molecular orbital Diagram shows that there are 16 bonding and 13 anti bonding electrons. The bonding order will be B O, equals 16 minus 13, Divided by two equals 1.5. And if we look at the lewis structure, we have iodine With three lone pairs connected to another iodine With three lone pairs connected to another iodine With three lone pairs connected to another iodine With three lone pairs. We see that a bond order of 1.5 is too small to hold this large molecule due to the low bond order. This molecule is too unstable to exist. Next we have be, If it were to exist in reality it would be a radical ion. iodine has seven valence electrons, I equals seven times Equals 28 electrons. One electron for the negative charge equals 29 electrons. Since the total number of electrons is odd, it will be radical. So B is true. So our final answers are true and true. Thank you for watching. Bye
Related Practice
Textbook Question

The following three Lewis structures can be drawn for N2O:

(b) The N—N bond length in N2O is 1.12 Å, slightly longer than a typical N ≡N bond; and the N— O bond length is 1.19 Å, slightly shorter than a typical N ═O bond (see Table 8.4). Based on these data, which resonance structure best represents N2O?

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Textbook Question

Ortho-Dichlorobenzene, C6H4Cl2, is obtained when two of the adjacent hydrogen atoms in benzene are replaced with Cl atoms. A skeleton of the molecule is shown here. (a) Complete a Lewis structure for the molecule using bonds and electron pairs as needed.

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Textbook Question

Ortho-Dichlorobenzene, C6H4Cl2, is obtained when two of the adjacent hydrogen atoms in benzene are replaced with Cl atoms. A skeleton of the molecule is shown here. (b) Are there any resonance structures for the molecule? If so, sketch them.

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Textbook Question

An important reaction for the conversion of natural gas to other useful hydrocarbons is the conversion of methane to ethane. 2 CH4(g) → C2H6(g) + H2(g) In practice, this reaction is carried out in the presence of oxygen, which converts the hydrogen produced into water. 2 CH4(g) + 12 O2(g) → C2H6(g) + H2O(g) Use Table 8.3 to estimate H for these two reactions. Why is the conversion of methane to ethane more favorable when oxygen is used? Why is the conversion of methane to ethane more favorable when oxygen is used?

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Textbook Question

Two compounds are isomers if they have the same chemical formula but different arrangements of atoms. Use Table 8.3 to estimate H for each of the following gas-phase isomerization reactions and indicate which isomer has the lower enthalpy. (d) Methyl isocyanide → Acetonitrile

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Textbook Question

The Ti2+ ion is isoelectronic with the Ca atom. (c) What charge would Ti have to be isoelectronic with Ca2+ ?

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