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Ch.8 - Basic Concepts of Chemical Bonding

Chapter 8, Problem 94a

Ortho-Dichlorobenzene, C6H4Cl2, is obtained when two of the adjacent hydrogen atoms in benzene are replaced with Cl atoms. A skeleton of the molecule is shown here. (a) Complete a Lewis structure for the molecule using bonds and electron pairs as needed.

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Hey everyone, we're asked to add the lone pairs to the following lewis structures. Now we know that iodine and chlorine are both in our group seven. A And since they're both in our group 7, 8, each should have seven valence electrons surrounding it. So starting off with our chlorine on our first compound, we have 12, 3, 4, 5, 6 and seven. So this will get us to our seven valence electrons for our chlorine. Now looking at her iodine, iodine currently has 1, 2 and three. Now, in order to complete that seven, we'll have to add two lone pairs. So now we have seven. Now going to our right structure, we're going to do the exact same thing except this time we have five of chlorine. So we know that our chlorine is going to have three lone pairs surrounding each one since we have one single bond bonded to our iodine. Now iodine has 1, 2, 3, 4 and five. Aydin has five valence electrons currently, so we'll need to add one lone pair to get to that seven. So these are going to be our final lewis structures. So I hope this made sense. And let us know if you have any questions
Related Practice
Textbook Question

The hypochlorite ion, ClO-, is the active ingredient in bleach. The perchlorate ion, ClO4-, is a main component of rocket propellants. Draw Lewis structures for both ions. (b) What is the formal charge of Cl in the perchlorate ion, assuming the Cl—O bonds are all single bonds?

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Textbook Question

The following three Lewis structures can be drawn for N2O:

(a) Using formal charges, which of these three resonance forms is likely to be the most important?

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Textbook Question

The following three Lewis structures can be drawn for N2O:

(b) The N—N bond length in N2O is 1.12 Å, slightly longer than a typical N ≡N bond; and the N— O bond length is 1.19 Å, slightly shorter than a typical N ═O bond (see Table 8.4). Based on these data, which resonance structure best represents N2O?

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Textbook Question

Ortho-Dichlorobenzene, C6H4Cl2, is obtained when two of the adjacent hydrogen atoms in benzene are replaced with Cl atoms. A skeleton of the molecule is shown here. (b) Are there any resonance structures for the molecule? If so, sketch them.

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Textbook Question

Consider the hypothetical molecule B-A=B. Are the following statements true or false? (a) This molecule cannot exist. (b) If resonance was important, the molecule would have identical A–B bond lengths.

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Textbook Question

An important reaction for the conversion of natural gas to other useful hydrocarbons is the conversion of methane to ethane. 2 CH4(g) → C2H6(g) + H2(g) In practice, this reaction is carried out in the presence of oxygen, which converts the hydrogen produced into water. 2 CH4(g) + 12 O2(g) → C2H6(g) + H2O(g) Use Table 8.3 to estimate H for these two reactions. Why is the conversion of methane to ethane more favorable when oxygen is used? Why is the conversion of methane to ethane more favorable when oxygen is used?

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