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Ch.7 - Periodic Properties of the Elements
Chapter 7, Problem 113d

When magnesium metal is burned in air (Figure 3.6), two products are produced. One is magnesium oxide, MgO. The other is the product of the reaction of Mg with molecular nitrogen, magnesium nitride. When water is added to magnesium nitride, it reacts to form magnesium oxide and ammonia gas. (d) Magnesium nitride can also be formed by reaction of the metal with ammonia at high temperature. Write a balanced equation for this reaction. If a 6.3-g Mg ribbon reacts with 2.57 g NH31g2 and the reaction goes to completion, which component is the limiting reactant? What mass of H21g2 is formed in the reaction?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Balancing Chemical Equations

Balancing chemical equations is essential in stoichiometry, ensuring that the number of atoms for each element is the same on both sides of the equation. This reflects the law of conservation of mass, which states that matter cannot be created or destroyed in a chemical reaction. To balance an equation, coefficients are adjusted to achieve equal atom counts, allowing for accurate predictions of product formation and reactant consumption.
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Limiting Reactants

The limiting reactant is the substance that is completely consumed first in a chemical reaction, thus determining the maximum amount of product that can be formed. To identify the limiting reactant, one must compare the mole ratios of the reactants based on the balanced equation and the initial amounts available. The reactant that produces the least amount of product is the limiting reactant, which is crucial for calculating yields.
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Stoichiometry

Stoichiometry is the quantitative relationship between reactants and products in a chemical reaction, allowing chemists to calculate the amounts of substances consumed and produced. It involves using molar ratios derived from a balanced equation to convert between grams, moles, and molecules. Understanding stoichiometry is vital for predicting how much product can be formed from given reactants and for determining the efficiency of a reaction.
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Related Practice
Textbook Question

One way to measure ionization energies is ultraviolet photoelectron spectroscopy (PES), a technique based on the photoelectric effect. (Section 6.2) In PES, monochromatic light is directed onto a sample, causing electrons to be emitted. The kinetic energy of the emitted electrons is measured. The difference between the energy of the photons and the kinetic energy of the electrons corresponds to the energy needed to remove the electrons (that is, the ionization energy). Suppose that a PES experiment is performed in which mercury vapor is irradiated with ultraviolet light of wavelength 58.4 nm. (d) Using Figure 7.10, determine which of the halogen elements has a first ionization energy closest to that of mercury.

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Textbook Question
Mercury in the environment can exist in oxidation states 0, +1, and +2. One major question in environmental chemistry research is how to best measure the oxidation state of mercury in natural systems; this is made more complicated by the fact that mercury can be reduced or oxidized on surfaces differently than it would be if it were free in solution. XPS, X-ray photoelectron spectroscopy, is a technique related to PES (see Exercise 7.111), but instead of using ultraviolet light to eject valence electrons, X rays are used to eject core electrons. The energies of the core electrons are different for different oxidation states of the element. In one set of experiments, researchers examined mercury contamination of minerals in water. They measured the XPS signals that corresponded to electrons ejected from mercury's 4f orbitals at 105 eV, from an X-ray source that provided 1253.6 eV of energy 11 ev = 1.602 * 10-19J2. The oxygen on the mineral surface gave emitted electron energies at 531 eV, corresponding to the 1s orbital of oxygen. Overall the researchers concluded that oxidation states were +2 for Hg and -2 for O. (b) Compare the energies of the 4f electrons in mercury and the 1s electrons in oxygen from these data to the first ionization energies of mercury and oxygen from the data in this chapter.
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Textbook Question

When magnesium metal is burned in air (Figure 3.6), two products are produced. One is magnesium oxide, MgO. The other is the product of the reaction of Mg with molecular nitrogen, magnesium nitride. When water is added to magnesium nitride, it reacts to form magnesium oxide and ammonia gas. (c) In an experiment, a piece of magnesium ribbon is burned in air in a crucible. The mass of the mixture of MgO and magnesium nitride after burning is 0.470 g. Water is added to the crucible, further reaction occurs, and the crucible is heated to dryness until the final product is 0.486 g of MgO. What was the mass percentage of magnesium nitride in the mixture obtained after the initial burning?

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Textbook Question

Potassium superoxide, KO2, is often used in oxygen masks (such as those used by firefighters) because KO2 reacts with CO2 to release molecular oxygen. Experiments indicate that 2 mol of KO2(s) react with each mole of CO2(g). (c) What mass of KO2(s) is needed to consume 18.0 g CO2(g)? What mass of O2(g) is produced during this reaction?

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