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Ch.7 - Periodic Properties of the Elements
Chapter 7, Problem 100

The first ionization energy of the oxygen molecule is the energy required for the following process: O21g2¡O2 +1g2 + e- The energy needed for this process is 1175 kJ>mol, very similar to the first ionization energy of Xe. Would you expect O2 to react with F2? If so, suggest a product or products of this reaction.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ionization Energy

Ionization energy is the amount of energy required to remove an electron from a gaseous atom or molecule. It is a critical factor in determining an element's reactivity, as elements with low ionization energies tend to lose electrons easily, while those with high ionization energies hold onto their electrons more tightly. The first ionization energy specifically refers to the energy needed to remove the outermost electron, which is relevant when considering the reactivity of O2 and its interaction with other elements.
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Reactivity of Oxygen

Oxygen is a highly reactive nonmetal that readily forms compounds with many elements, particularly halogens like fluorine. Its reactivity is influenced by its electronegativity and the ability to accept electrons, which allows it to form stable bonds with other elements. When considering a reaction between O2 and F2, one must account for the strong oxidizing nature of both species, leading to the formation of products such as oxygen difluoride (OF2).
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Fluorine as a Reactant

Fluorine is the most electronegative element and is known for its high reactivity, often forming compounds with other elements by accepting electrons. In reactions with oxygen, fluorine can lead to the formation of various oxides, depending on the conditions. The strong bond formation between fluorine and oxygen results in the release of energy, making the reaction favorable and leading to products like OF2 or O2F2, which are important in various chemical applications.
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Related Practice
Textbook Question

Which of the following chemical equations is connected to the definitions of (a) the first ionization energy of oxygen (i) O1g2 + e-¡O-1g2 (ii) O1g2¡O+1g2 + e- (iii) O1g2 + 2 e-¡O2-1g2 (iv) O1g2¡O2+1g2 + 2 e- (v) O+1g2¡O2+1g2 + e-

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Textbook Question
The electron affinities, in kJ>mol, for the group 11 and group 12 metals are as follows: Cu -119 Zn 7 0 Ag -126 Cd 7 0 Au -223 Hg 7 0 (b) Why do the electron affinities of the group 11 elements become more negative as we move down the group? [Hint: Examine the trends in the electron affinities of other groups as we proceed down the periodic table.]

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Textbook Question

Hydrogen is an unusual element because it behaves in some ways like the alkali metal elements and in other ways like nonmetals. Its properties can be explained in part by its electron configuration and by the values for its ionization energy and electron affinity. (a) Explain why the electron affinity of hydrogen is much closer to the values for the alkali elements than for the halogens.

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Textbook Question

It is possible to define metallic character as we do in this book and base it on the reactivity of the element and the ease with which it loses electrons. Alternatively, one could measure how well electricity is conducted by each of the elements to determine how 'metallic' the elements are. On the basis of conductivity, there is not much of a trend in the periodic table: Silver is the most conductive metal, and manganese the least. Look up the first ionization energies of silver and manganese; which of these two elements would you call more metallic based on the way we define it in this book?

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Textbook Question

Which of the following is the expected product of the reaction of K(s) and H2(g)? (i) KH(s), (ii) K2H(s), (iii) KH2(s), (iv) K2H2(s), or (v) K(s) and H2(g) will not react with one another.

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Textbook Question

A historian discovers a nineteenth-century notebook in which some observations, dated 1822, were recorded on a substance thought to be a new element. Here are some of the data recorded in the notebook: 'Ductile, silver-white, metallic looking. Softer than lead. Unaffected by water. Stable in air. Melting point: 153 °C. Density: 7.3 g>cm3. Electrical conductivity: 20% that of copper. Hardness: About 1% as hard as iron. When 4.20 g of the unknown is heated in an excess of oxygen, 5.08 g of a white solid is formed. The solid could be sublimed by heating to over 800 °C.' (a) Using information in the text and the CRC Handbook of Chemistry and Physics, and making allowances for possible variations in numbers from current values, identify the element reported.

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