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Ch.7 - Periodic Properties of the Elements

Chapter 7, Problem 24

The experimental Pb¬Cl bond length in lead(II)chloride, PbCl2, is 244 pm. Based on this value and data in Figure 7.7, predict the atomic radius of Pb.

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Hi everyone here, we have a question asking us given the atomic radius of the elements to determine the atomic radius of cesium. If the experimental bonding for cesium selenium is 4. angstrom. So we need to find selenium on our table here and it is right here. Its length is 117 PICO meters. So we need to convert that to angstrom. So we have selenium 117 PICO m times one angstrom Over 100 m. Our Picom will cancel out and that will give us 1.17 angstrom size. Our cesium selenium bond Is 4. Angstrom. So we need to subtract our 1.17 angstrom. That accounts for the selenium. So we'll just be left with cesium And that equals 3.01 Angstrom. And that is our final answer. Thank you for watching. Bye.
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Tungsten has the highest melting point of any metal in the periodic table: 3422 °C. The distance between W atoms in tungsten metal is 274 pm. (b) If you put tungsten metal under high pressure, predict what would happen to the distance between W atoms.

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Textbook Question

Which of the following statements about the bonding atomic radii in Figure 7.7 is incorrect? (i) For a given period, the radii of the representative elements generally decrease from left to right across a period. (ii) The radii of the representative elements for the n = 3 period are all larger than those of the corresponding elements in the n = 2 period. (iii) For most of the representative elements, the change in radius from the n = 2 to the n = 3 period is greater than the change in radius from n = 3 to n = 4. (iv) The radii of the transition elements generally increase moving from left to right within a period. (v) The large radii of the Group 1 elements are due to their relatively small effective nuclear charges.

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Estimate the As¬I bond length from the data in Figure 7.7 and compare your value to the experimental As ¬I bond length in arsenic triiodide, AsI3, 2.55 Å.

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