Chapter 7, Problem 24
The experimental Pb¬Cl bond length in lead(II)chloride, PbCl2, is 244 pm. Based on this value and data in Figure 7.7, predict the atomic radius of Pb.
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Tungsten has the highest melting point of any metal in the periodic table: 3422 °C. The distance between W atoms in tungsten metal is 274 pm. (b) If you put tungsten metal under high pressure, predict what would happen to the distance between W atoms.
Which of the following statements about the bonding atomic radii in Figure 7.7 is incorrect? (i) For a given period, the radii of the representative elements generally decrease from left to right across a period. (ii) The radii of the representative elements for the n = 3 period are all larger than those of the corresponding elements in the n = 2 period. (iii) For most of the representative elements, the change in radius from the n = 2 to the n = 3 period is greater than the change in radius from n = 3 to n = 4. (iv) The radii of the transition elements generally increase moving from left to right within a period. (v) The large radii of the Group 1 elements are due to their relatively small effective nuclear charges.
Estimate the As¬I bond length from the data in Figure 7.7 and compare your value to the experimental As ¬I bond length in arsenic triiodide, AsI3, 2.55 Å.
Using only the periodic table, arrange each set of atoms in order from largest to smallest: (c) F, O, N.
Using only the periodic table, arrange each set of atoms in order of increasing radius: (b) S, Si, Sr
Identify each statement as true or false: (a) Cations are larger than their corresponding neutral atoms.