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Ch.7 - Periodic Properties of the Elements
Chapter 7, Problem 37

Write equations that show the processes that describe the first, second, and third ionization energies of a chlorine atom. Which process would require the least amount of energy?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ionization Energy

Ionization energy is the energy required to remove an electron from a gaseous atom or ion. It is a measure of how strongly an atom holds onto its electrons. The first ionization energy refers to the removal of the first electron, while subsequent ionization energies involve removing additional electrons from the resulting cations. Generally, ionization energy increases with each successive electron removed due to the increasing positive charge of the ion.
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Chlorine Atom and Its Electron Configuration

Chlorine (Cl) has an atomic number of 17, meaning it has 17 electrons arranged in its electron configuration as [Ne] 3s² 3p⁵. The outermost electrons, particularly those in the 3s and 3p orbitals, are involved in ionization processes. Understanding the electron configuration is crucial for predicting how many electrons can be removed and the energy changes associated with these removals.
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Trends in Ionization Energies

Ionization energies exhibit periodic trends; they generally increase across a period and decrease down a group in the periodic table. For chlorine, the first ionization energy is lower than the second and third because removing an electron from a neutral atom is easier than removing one from a positively charged ion. Therefore, the first ionization energy will require the least amount of energy compared to the second and third ionization energies.
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