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Ch.5 - Thermochemistry
Chapter 5, Problem 31

During a deep breath, our lungs expand about 2.0 L against an external pressure of 101.3 kPa. How much work is involved in this process (in J)?

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Identify the formula for work done by a gas: \( w = -P_{\text{ext}} \Delta V \), where \( w \) is the work done, \( P_{\text{ext}} \) is the external pressure, and \( \Delta V \) is the change in volume.
Convert the volume change from liters to cubic meters, since 1 L = 0.001 m³. Therefore, \( \Delta V = 2.0 \text{ L} \times 0.001 \text{ m}^3/\text{L} \).
Substitute the given values into the formula: \( w = -(101.3 \text{ kPa}) \times (\Delta V \text{ in m}^3) \).
Convert the pressure from kilopascals to pascals, knowing that 1 kPa = 1000 Pa, so \( 101.3 \text{ kPa} = 101300 \text{ Pa} \).
Calculate the work done using the values in the formula, keeping in mind that the work will be in joules (J) since 1 Pa = 1 N/m² and 1 J = 1 N·m.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Work in Thermodynamics

In thermodynamics, work is defined as the energy transferred when a force is applied over a distance. For gas expansion or compression, work can be calculated using the formula W = -PΔV, where W is work, P is the external pressure, and ΔV is the change in volume. The negative sign indicates that work is done by the system when it expands.
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Pressure-Volume Work

Pressure-volume work occurs when a gas expands or contracts against an external pressure. The work done by the gas during expansion is directly proportional to the pressure exerted and the change in volume. Understanding this relationship is crucial for calculating the work done during processes like breathing, where lung volume changes against atmospheric pressure.
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Units of Measurement

In this context, work is measured in joules (J), which is the SI unit of energy. One joule is defined as the work done when a force of one newton displaces an object by one meter. It is important to ensure that all units are consistent when performing calculations, particularly when converting pressure from kilopascals to pascals or volume from liters to cubic meters.
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Related Practice
Textbook Question

A gas is confined to a cylinder fitted with a piston and an electrical heater, as shown here:

Suppose that current is supplied to the heater so that 100 J of energy is added. Consider two different situations. In case (1) the piston is allowed to move as the energy is added. In case (2) the piston is fixed so that it cannot move. (b) Identify the sign (positive, negative, or zero) of q and w in each case?

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Textbook Question

Consider a system consisting of two oppositely charged spheres hanging by strings and separated by a distance r1, as shown in the accompanying illustration. Suppose they are separated to a larger distance r2, by moving them apart. (a) What change, if any, has occurred in the potential energy of the system?

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Textbook Question

(c) Is the volume of a system a state function? Why or why not?

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Textbook Question
How much work (in J) is involved in a chemical reaction if the volume decreases from 33.6 L to 11.2 L against a constant pressure of 90.5 kPa?
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Open Question
(c) For a given process at constant pressure, _x001F_H is negative. Is the process endothermic or exothermic?
Open Question
(a) Under what condition will the enthalpy change of a process equal the amount of heat transferred into or out of the system? (b) During a constant-pressure process, the system releases heat to the surroundings. Does the enthalpy of the system increase or decrease during the process? (c) In a constant-pressure process, _x001F_H = 0. What can you conclude about _x001F_E, q, and w?