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Ch.5 - Thermochemistry
Chapter 5, Problem 27b

A gas is confined to a cylinder fitted with a piston and an electrical heater, as shown here:
Illustration of a gas cylinder with a piston and heater for thermodynamics study.
Suppose that current is supplied to the heater so that 100 J of energy is added. Consider two different situations. In case (1) the piston is allowed to move as the energy is added. In case (2) the piston is fixed so that it cannot move. (b) Identify the sign (positive, negative, or zero) of q and w in each case?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

First Law of Thermodynamics

The First Law of Thermodynamics states that energy cannot be created or destroyed, only transformed from one form to another. In the context of the gas in the cylinder, the energy added as heat (q) can either increase the internal energy of the gas or do work (w) on the piston, depending on whether the piston is allowed to move.
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First Law of Thermodynamics

Heat (q) and Work (w)

In thermodynamics, heat (q) refers to the energy transferred due to temperature differences, while work (w) is the energy transferred when a force is applied over a distance. In the scenarios presented, the movement of the piston affects how energy is distributed between heat and work, influencing their signs based on the system's constraints.
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System Constraints

The constraints of a system, such as whether the piston can move or is fixed, significantly impact the thermodynamic processes occurring. In case (1), the piston moves, allowing the gas to do work on the surroundings, while in case (2), the fixed piston means no work is done, affecting the signs of q and w differently in each scenario.
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Related Practice
Textbook Question

Calculate ΔE and determine whether the process is endothermic or exothermic for the following cases: (a) q = 0.763 kJ and w = -840 J.

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Textbook Question

For the following processes, calculate the change in internal energy of the system and determine whether the process is endothermic or exothermic: (a) A balloon is cooled by removing 0.655 kJ of heat. It shrinks on cooling, and the atmosphere does 382 J of work on the balloon.

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Textbook Question

A gas is confined to a cylinder fitted with a piston and an electrical heater, as shown here:

Suppose that current is supplied to the heater so that 100 J of energy is added. Consider two different situations. In case (1) the piston is allowed to move as the energy is added. In case (2) the piston is fixed so that it cannot move. (a) In which case does the gas have the higher temperature after addition of the electrical energy?

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Textbook Question

Consider a system consisting of two oppositely charged spheres hanging by strings and separated by a distance r1, as shown in the accompanying illustration. Suppose they are separated to a larger distance r2, by moving them apart. (a) What change, if any, has occurred in the potential energy of the system?

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Textbook Question

(c) Is the volume of a system a state function? Why or why not?

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Textbook Question
During a deep breath, our lungs expand about 2.0 L against an external pressure of 101.3 kPa. How much work is involved in this process (in J)?
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