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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 1

Which of the following schematic drawings best describes a solution of Li2SO4 in water (water molecules not shown for simplicity)?

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Understand the composition of Li2SO4: Lithium sulfate (Li2SO4) is an ionic compound composed of two lithium ions (Li^+) and one sulfate ion (SO4^2-).
Consider the dissociation in water: When Li2SO4 dissolves in water, it dissociates into its constituent ions. This means that each formula unit of Li2SO4 will produce two Li^+ ions and one SO4^2- ion.
Visualize the solution: In the solution, you will have a mixture of Li^+ ions and SO4^2- ions dispersed throughout the water. The water molecules, although not shown, are surrounding and stabilizing these ions.
Identify the correct schematic: The correct schematic should show twice as many Li^+ ions as SO4^2- ions, reflecting the stoichiometry of the dissociation process.
Check for charge balance: Ensure that the total positive charge from the Li^+ ions equals the total negative charge from the SO4^2- ions, maintaining electrical neutrality in the solution.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ionic Compounds in Solution

Ionic compounds, like Li2SO4, dissociate into their constituent ions when dissolved in water. In this case, lithium ions (Li+) and sulfate ions (SO4^2-) separate and disperse throughout the solution. Understanding this dissociation is crucial for visualizing how ionic compounds interact with solvent molecules.
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Solvation Process

Solvation refers to the process by which solvent molecules surround and interact with solute ions or molecules. In the case of Li2SO4 in water, water molecules will orient themselves around the Li+ and SO4^2- ions, stabilizing them in solution. This concept is essential for understanding the behavior of ions in an aqueous environment.
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Schematic Representations of Solutions

Schematic drawings are simplified representations that illustrate the arrangement of particles in a solution. For Li2SO4 in water, a correct schematic would show the dissociated Li+ and SO4^2- ions distributed throughout the drawing, highlighting their interactions with the solvent. This visual representation aids in comprehending the molecular dynamics within the solution.
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