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Ch.3 - Chemical Reactions and Reaction Stoichiometry
Chapter 3, Problem 59

Washing soda, a compound used to prepare hard water for washing laundry, is a hydrate, which means that a certain number of water molecules are included in the solid structure. Its formula can be written as Na2CO3 # xH2O, where x is the number of moles of H2O per mole of Na2CO3. When a 2.558-g sample of washing soda is heated at 125 C, all the water of hydration is lost, leaving 0.948 g of Na2CO3. What is the value of x?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Hydrates

Hydrates are compounds that contain water molecules within their crystalline structure. The general formula for a hydrate is represented as a salt followed by a certain number of water molecules, denoted as 'xH2O'. The water molecules are integral to the structure and can be removed through heating, which is essential for determining the composition of the hydrate.
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Molar Mass and Mass Loss

To find the value of 'x' in a hydrate, one must understand the concept of molar mass, which is the mass of one mole of a substance. By calculating the mass of the hydrate before and after heating, the mass loss corresponds to the water of hydration. This mass loss can be used to determine the number of moles of water lost, which is crucial for finding 'x' in the formula Na2CO3 # xH2O.
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Stoichiometry

Stoichiometry is the area of chemistry that deals with the quantitative relationships between reactants and products in a chemical reaction. In the context of hydrates, stoichiometry allows us to relate the moles of Na2CO3 remaining after heating to the moles of water lost. This relationship is essential for calculating the value of 'x' in the hydrate formula.
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Related Practice
Textbook Question

(b) Nicotine, a component of tobacco, is composed of C, H, and N. A 5.250-mg sample of nicotine was combusted, producing 14.242 mg of CO2 and 4.083 mg of H2O. What is the empirical formula for nicotine? If nicotine has a molar mass of 160 ± 5 g/mol, what is its molecular formula?

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Textbook Question

Valproic acid, used to treat seizures and bipolar disorder, is composed of C, H, and O. A 0.165-g sample is combusted to produce 0.166 g of water and 0.403 g of carbon dioxide. What is the empirical formula for valproic acid?

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Textbook Question

Propenoic acid, C3H4O2, is a reactive organic liquid that is used in the manufacturing of plastics, coatings, and adhesives. An unlabeled container is thought to contain this liquid. A 0.275-g sample of the liquid is combusted to produce 0.102 g of water and 0.374 g carbon dioxide. Is the unknown liquid propenoic acid? Support your reasoning with calculations.

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Textbook Question

Epsom salts, a strong laxative used in veterinary medicine, is a hydrate, which means that a certain number of water molecules are included in the solid structure. The formula for Epsom salts can be written as MgSO4 # xH2O, where x indicates the number of moles of H2O per mole of MgSO4. When 5.061 g of this hydrate is heated to 250 C, all the water of hydration is lost, leaving 2.472 g of MgSO4. What is the value of x?

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Textbook Question

Hydrofluoric acid, HF(aq), cannot be stored in glass bottles because compounds called silicates in the glass are attacked by the HF(aq). Sodium silicate 1Na2SiO32, for example, reacts as follows: Na2SiO31s2 + 8 HF1aq2¡ H2SiF61aq2 + 2 NaF1aq2 + 3 H2O1l2 (b) How many grams of NaF form when 0.500 mol of HF reacts with excess Na2SiO3?

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Textbook Question

The reaction between potassium superoxide, KO2, and CO2, 4 KO2 + 2 CO2¡2K2CO3 + 3 O2 is used as a source of O2 and absorber of CO2 in selfcontained breathing equipment used by rescue workers. (a) How many moles of O2 are produced when 0.400 mol of KO2 reacts in this fashion?

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