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Ch.3 - Chemical Reactions and Reaction Stoichiometry

Chapter 3, Problem 115d

The thermite reaction, Fe2O3 + Al S Al2O3 + Fe produces so much heat that the Fe product melts. This reaction is used industrially to weld metal parts under water, where a torch cannot be employed. It is also a favorite chemical demonstration in the lecture hall (on a small scale). (d) If you performed the reverse reaction— aluminum oxide plus iron makes iron oxide plus aluminum—would that reaction have heat as a reactant or a product?

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Hello everyone. So first I'm going to go ahead and informally translate all these words in the problem into a chemical reaction. I say informally because I'm not going to go ahead and write the proper chemical reaction. I just want to roughly translate this to see what exactly is going on in a chemical in a chemistry point of view. And so we can see here. So let's first state that we're going to go ahead and write out the forward reaction, saying that the potassium reacts intensely with water to form potassium hydroxide and highly flammable hydrogen. So it says that the reaction can cause a small explosion due to heat released, igniting the hydrogen. So it's saying that the heat is released, meaning that heat is going to be one of our by products. So we have heat as well. And it's asking in this problem if that the reverse reaction is going to have the heat being the starting material or our product. And so our reverse reaction, basically what we're doing here is not now the products is going to be our starting materials and our star materials are going to be our products. So we just kind of flipping it around. So we have the K. O. H. Are highly flammable hydrogen and we have the heat byproduct as now are starting materials and our new products is going to be the potassium and the water. So, as you can see from this chemistry, right chemical occasion right here is that now we have the heat being a reactant and not a product. So, to properly answer this question. So my answer is that heat is a reactant and the reverse reaction, and that is going to be my final answer for this problem. Thank you all so much for watching.
Related Practice
Textbook Question

The source of oxygen that drives the internal combustion engine in an automobile is air. Air is a mixture of gases, principally N2179%2 and O2120%2. In the cylinder of an automobile engine, nitrogen can react with oxygen to produce nitric oxide gas, NO. As NO is emitted from the tailpipe of the car, it can react with more oxygen to produce nitrogen dioxide gas. (b) Both nitric oxide and nitrogen dioxide are pollutants that can lead to acid rain and global warming; collectively, they are called 'NOx' gases. In 2009, the United States emitted an estimated 19 million tons of nitrogen dioxide into the atmosphere. How many grams of nitrogen dioxide is this?

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Textbook Question

The source of oxygen that drives the internal combustion engine in an automobile is air. Air is a mixture of gases, principally N2(79%) and O2(20%). In the cylinder of an automobile engine, nitrogen can react with oxygen to produce nitric oxide gas, NO. As NO is emitted from the tailpipe of the car, it can react with more oxygen to produce nitrogen dioxide gas. (c) The production of NOx gases is an unwanted side reaction of the main engine combustion process that turns octane, C8H18, into CO2 and water. If 85% of the oxygen in an engine is used to combust octane and the remainder used to produce nitrogen dioxide, calculate how many grams of nitrogen dioxide would be produced during the combustion of 500 g of octane.

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Textbook Question

The thermite reaction, Fe2O3 + Al → Al2O3 + Fe produces so much heat that the Fe product melts. This reaction is used industrially to weld metal parts under water, where a torch cannot be employed. It is also a favorite chemical demonstration in the lecture hall (on a small scale). (b) Calculate how many grams of aluminum are needed to completely react with 500.0 g of Fe2O3 in this reaction.

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Textbook Question
One of the most bizarre reactions in chemistry is called the Ugi reaction: R1C(=O)R2 + R3 - NH2 + R4COOH + R5NC S R4C(=O)N(R3)C(R1R2)C=ONHR5 + H2O

(a) Write out the balanced chemical equation for the Ugi reaction, for the case where R = CH3CH2CH2CH2CH2CH2— (this is called the hexyl group) for all compounds.
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