(b) Why is the actual yield in a reaction almost always less than the theoretical yield?
Ch.3 - Chemical Reactions and Reaction Stoichiometry
Chapter 3, Problem 75c
Consider the mixture of ethanol, C2H5OH, and O2 shown in the accompanying diagram. (c) How many molecules of CO2, H2O, C2H5OH, and O2 will be present if the reaction goes to completion?
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Identify the balanced chemical equation for the combustion of ethanol (C2H5OH). The equation is: C2H5OH + 3 O2
ightarrow 2 CO2 + 3 H2O.
Determine the limiting reactant by comparing the mole ratio of C2H5OH to O2 in the reaction equation with the mole ratio provided in the diagram.
Calculate the number of moles of CO2 and H2O produced based on the stoichiometry of the balanced equation and the amount of the limiting reactant.
Since the reaction goes to completion, all of the limiting reactant will be consumed. Calculate the remaining amount of the excess reactant, if any.
Convert the moles of CO2, H2O, and any remaining reactants back to the number of molecules using Avogadro's number (6.022 x 10^23 molecules/mole).
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Stoichiometry
Stoichiometry is the branch of chemistry that deals with the quantitative relationships between the reactants and products in a chemical reaction. It allows us to calculate the amounts of substances consumed and produced in a reaction based on balanced chemical equations. Understanding stoichiometry is essential for determining how many molecules of each substance will be present after a reaction goes to completion.
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Balancing Chemical Equations
Balancing chemical equations is the process of ensuring that the number of atoms for each element is the same on both sides of the equation. This is crucial for accurately representing the conservation of mass during a chemical reaction. In the context of the given question, balancing the equation for the combustion of ethanol will provide the necessary ratios to calculate the amounts of CO2, H2O, C2H5OH, and O2 produced or consumed.
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Limiting Reactant
The limiting reactant is the substance that is completely consumed first in a chemical reaction, thus determining the maximum amount of product that can be formed. Identifying the limiting reactant is vital for calculating the final quantities of products and remaining reactants after the reaction has gone to completion. In the case of the ethanol and O2 mixture, knowing which reactant limits the reaction will help in determining the final amounts of CO2 and H2O produced.
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Related Practice
Textbook Question
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Textbook Question
(c) Can a reaction ever have 110% actual yield?
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Textbook Question
Consider the mixture of ethanol, C2H5OH, and O2 shown in the accompanying diagram. (b) Which reactant is the limiting reactant?
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Textbook Question
Consider the mixture of propane, C3H8, and O2 shown here. (a) Write a balanced equation for the combustion reaction that occurs between propane and oxygen.
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Textbook Question
Consider the mixture of propane, C3H8, and O2 shown here. (c) How many molecules of CO2, H2O, C3H8, and O2 will be present if the reaction goes to completion?
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Textbook Question
Sodium hydroxide reacts with carbon dioxide as follows: 2 NaOH(s) + CO2(g) → Na2CO3(s) + H2O(l) Which is the limiting reactant when 1.85 mol NaOH and 1.00 mol CO2 are allowed to react?