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Ch.3 - Chemical Reactions and Reaction Stoichiometry
Chapter 3, Problem 99a

A method used by the U.S. Environmental Protection Agency (EPA) for determining the concentration of ozone in air is to pass the air sample through a 'bubbler' containing sodium iodide, which removes the ozone according to the following equation: O31g2 + 2 NaI1aq2 + H2O1l2¡ O21g2 + I21s2 + 2 NaOH1aq2 (a) How many moles of sodium iodide are needed to remove 5.95 * 10-6 mol of O3?

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Identify the balanced chemical equation: \( \text{O}_3(g) + 2 \text{NaI}(aq) + \text{H}_2\text{O}(l) \rightarrow \text{O}_2(g) + \text{I}_2(s) + 2 \text{NaOH}(aq) \).
Determine the stoichiometric relationship between \( \text{O}_3 \) and \( \text{NaI} \) from the balanced equation. For every mole of \( \text{O}_3 \), 2 moles of \( \text{NaI} \) are required.
Calculate the moles of \( \text{NaI} \) needed using the stoichiometric ratio: \( 2 \text{ moles NaI} / 1 \text{ mole O}_3 \).
Multiply the given moles of \( \text{O}_3 \) by the stoichiometric ratio to find the moles of \( \text{NaI} \) needed: \( 5.95 \times 10^{-6} \text{ mol O}_3 \times \frac{2 \text{ mol NaI}}{1 \text{ mol O}_3} \).
Perform the multiplication to determine the moles of \( \text{NaI} \) required.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Stoichiometry

Stoichiometry is the branch of chemistry that deals with the quantitative relationships between the reactants and products in a chemical reaction. It allows us to calculate how much of a substance is needed or produced based on the balanced chemical equation. In this case, understanding the stoichiometric coefficients from the reaction equation is essential to determine the moles of sodium iodide required to react with a given amount of ozone.
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Stoichiometry Concept

Mole Concept

The mole concept is a fundamental principle in chemistry that defines the amount of substance. One mole corresponds to 6.022 x 10²³ entities (atoms, molecules, etc.). This concept is crucial for converting between the mass of a substance and the number of moles, allowing us to relate the quantities of reactants and products in a chemical reaction, such as the amount of sodium iodide needed to react with ozone.
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Balancing Chemical Equations

Balancing chemical equations is the process of ensuring that the number of atoms for each element is the same on both sides of the equation. This is important because it reflects the conservation of mass in a chemical reaction. In the provided reaction, the coefficients indicate the molar ratios of ozone and sodium iodide, which are necessary for calculating the required moles of sodium iodide to completely react with the specified amount of ozone.
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Related Practice
Textbook Question

An organic compound was found to contain only C, H, and Cl. When a 1.50-g sample of the compound was completely combusted in air, 3.52 g of CO2 was formed. In a separate experiment, the chlorine in a 1.00-g sample of the compound was converted to 1.27 g of AgCl. Determine the empirical formula of the compound.

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Textbook Question
A compound, Na2Cr2Ox, where x is unknown, is analyzed and found to contain 39.70% Cr. What is the value of x?
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Textbook Question

An element X forms an iodide 1XI32 and a chloride 1XCl32. The iodide is quantitatively converted to the chloride when it is heated in a stream of chlorine: 2 XI3 + 3 Cl2¡2 XCl3 + 3 I2 If 0.5000 g of XI3 is treated with chlorine, 0.2360 g of XCl3 is obtained. (a) Calculate the atomic weight of the element X.

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Textbook Question

A method used by the U.S. Environmental Protection Agency (EPA) for determining the concentration of ozone in air is to pass the air sample through a 'bubbler' containing sodium iodide, which removes the ozone according to the following equation: O31g2 + 2 NaI1aq2 + H2O1l2¡ O21g2 + I21s2 + 2 NaOH1aq2 (b) How many grams of sodium iodide are needed to remove 1.3 mg of O3?

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Textbook Question

The fat stored in a camel's hump is a source of both energy and water. Calculate the mass of H2O produced by the metabolism of 1.0 kg of fat, assuming the fat consists entirely of tristearin 1C57H110O62, a typical animal fat, and assuming that during metabolism, tristearin reacts with O2 to form only CO2 and H2O.

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Open Question
When hydrocarbons are burned in a limited amount of air, both CO and CO2 form. When 0.450 g of a particular hydrocarbon was burned in air, 0.467 g of CO, 0.733 g of CO2, and 0.450 g of H2O were formed. (a) What is the empirical formula of the compound? (b) How many grams of O2 were used in the reaction? (c) How many grams would have been required for complete combustion?