Chapter 3, Problem 112
A 3.50 g of an alloy which contains only lead and tin is dissolved in hot HNO3. Excess sulfuric acid is added to this solution and 1.57g of PbSO4(s) is obtained. (b) Assuming all the lead in the alloy reacted to form PbSO4, what was the amount, in grams, of lead and tin in the alloy respectively?
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A mixture containing KClO3, K2CO3, KHCO3, and KCl was heated, producing CO2, O2, and H2O gases according to the following equations: 2 KClO31s2¡2 KCl1s2 + 3 O21g2 2 KHCO31s2¡K2O1s2 + H2O1g2 + 2 CO21g2 K2CO31s2¡K2O1s2 + CO21g2 The KCl does not react under the conditions of the reaction. If 100.0 g of the mixture produces 1.80 g of H2O, 13.20 g of CO2, and 4.00 g of O2, what was the composition of the original mixture? (Assume complete decomposition of the mixture.) How many grams of K2CO3 were in the original mixture?
Burning acetylene in oxygen can produce three different carbon-containing products: soot (very fine particles of graphite), CO(g), and CO2(g). (c) Why, when the oxygen supply is adequate, is CO2(g) the predominant carbon-containing product of the combustion of acetylene?
Hydrogen cyanide, HCN, is a poisonous gas. The lethal dose is approximately 300 mg HCN per kilogram of air when inhaled. (a) Calculate the amount of HCN that gives the lethal dose in a small laboratory room measuring 3.5 * 4.5 * 2.5 m. The density of air at 26 C is 0.00118 g>cm3.
Hydrogen cyanide, HCN, is a poisonous gas. The lethal dose is approximately 300 mg HCN per kilogram of air when inhaled. (c) HCN forms when synthetic fibers containing Orlon® or Acrilan ® burn. Acrilan® has an empirical formula of CH2CHCN, so HCN is 50.9% of the formula by mass. A rug measures 3.5 * 4.5 m and contains 850 g of Acrilan® fibers per square yard of carpet. If the rug burns, will a lethal dose of HCN be generated in the room? Assume that the yield of HCN from the fibers is 20% and that the carpet is 50% consumed.
The source of oxygen that drives the internal combustion engine in an automobile is air. Air is a mixture of gases, principally N2179%2 and O2120%2. In the cylinder of an automobile engine, nitrogen can react with oxygen to produce nitric oxide gas, NO. As NO is emitted from the tailpipe of the car, it can react with more oxygen to produce nitrogen dioxide gas. (b) Both nitric oxide and nitrogen dioxide are pollutants that can lead to acid rain and global warming; collectively, they are called 'NOx' gases. In 2009, the United States emitted an estimated 19 million tons of nitrogen dioxide into the atmosphere. How many grams of nitrogen dioxide is this?