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Ch.23 - Transition Metals and Coordination Chemistry
Chapter 23, Problem 12

Complete the exercises below. Which periodic trend is partially responsible for the observation that the maximum oxidation state of the transition-metal elements peaks near groups 7B and 8B? a. The number of valence electrons reaches a maximum at group 8B. b. The effective nuclear charge increases on moving right across each period. c. The radii of the transition-metal elements reach a minimum for group 8B, and as the size of the atoms decreases it becomes easier to remove electrons.

Verified step by step guidance
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Step 1: Understand the periodic trends involved in the problem. The periodic table shows trends in properties such as atomic radius, ionization energy, and effective nuclear charge as you move across a period or down a group.
Step 2: Consider the trend of the number of valence electrons. In transition metals, the number of valence electrons generally increases as you move from left to right across a period, reaching a maximum at group 8B.
Step 3: Analyze the effective nuclear charge trend. As you move across a period from left to right, the effective nuclear charge experienced by the valence electrons increases, which can affect the ability of an atom to lose or gain electrons.
Step 4: Examine the trend in atomic radii. The atomic radius generally decreases across a period due to the increasing effective nuclear charge, which pulls the electron cloud closer to the nucleus.
Step 5: Relate these trends to the oxidation states of transition metals. The maximum oxidation state of transition metals is influenced by the number of valence electrons and the effective nuclear charge, which affects the ease of electron removal. Consider how these factors peak around groups 7B and 8B.
Related Practice
Textbook Question

Which of these crystal-field splitting diagrams represents:

a. a weak-field octahedral complex of Fe³⁺ ,

b. a strong-field octahedral complex of Fe³⁺ 

c. a tetrahedral complex of Fe³⁺

d. a tetrahedral complex of Ni²⁺ (The diagrams do not indicate the relative magnitudes of ∆. ) [Find more in Section 23.6.]

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Textbook Question

In the linear crystal-field shown here, the negative charges are on the z-axis. Using Figure 23.28 as a guide, predict which of the following choices most accurately describes the splitting of the d orbitals in a linear crystal-field? [Find more in Section 23.6.]                                                                                                                                                

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Open Question
Complete the exercises below. The lanthanide contraction explains which of the following periodic trends? a. The atomic radii of the transition metals first decrease and then increase when moving horizontally across each period. b. When forming ions, the period 4 transition metals lose their 4s electrons before their 3d electrons. c. The radii of the period 5 transition metals (Y–Cd) are very similar to the radii of the period 6 transition metals (Lu–Hg).
Open Question
Complete the exercises below. For each of the following compounds, determine the electron configuration of the transition-metal ion. a. TiO, b. TiO₂, c. NiO, d. ZnO.
Open Question
Among the period 4 transition metals (Sc–Zn), which elements do not form ions with partially filled 3d orbitals?
Textbook Question

Write out the ground-state electron configurations of b. Ru²⁺

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