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Ch.21 - Nuclear Chemistry
Chapter 21, Problem 87

A 53.8-mg sample of sodium perchlorate contains radioactive chlorine-36 (whose atomic mass is 36.0 amu). If 29.6% of the chlorine atoms in the sample are chlorine-36 and the remainder are naturally occurring nonradioactive chlorine atoms, how many disintegrations per second are produced by this sample? The half-life of chlorine-36 is 3.0 * 105 yr.

Verified step by step guidance
1
Convert the mass of the sodium perchlorate sample from milligrams to grams by dividing by 1000.
Calculate the molar mass of sodium perchlorate (NaClO₄) using the atomic masses of sodium (Na), chlorine (Cl), and oxygen (O).
Determine the number of moles of sodium perchlorate in the sample by dividing the mass of the sample in grams by the molar mass of sodium perchlorate.
Calculate the total number of chlorine atoms in the sample by multiplying the number of moles of sodium perchlorate by Avogadro's number (6.022 x 10²³ atoms/mol).
Find the number of chlorine-36 atoms by multiplying the total number of chlorine atoms by the percentage of chlorine-36 (29.6%).
Related Practice
Open Question
The Sun radiates energy into space at the rate of 3.9 * 1026 J/s. (a) Calculate the rate of mass loss from the Sun in kg/s. (b) How does this mass loss arise? (c) It is estimated that the Sun contains 9 * 1056 free protons. How many protons per second are consumed in nuclear reactions in the Sun?
Open Question
The average energy released in the fission of a single uranium-235 nucleus is about 3 * 10^-11 J. If the conversion of this energy to electricity in a nuclear power plant is 40% efficient, what mass of uranium-235 undergoes fission in a year in a plant that produces 1000 megawatts? Recall that a watt is 1 J/s.
Open Question
Tests on human subjects in Boston in 1965 and 1966, following the era of atomic bomb testing, revealed average quantities of about 2 pCi of plutonium radioactivity in the average person. How many disintegrations per second does this level of activity imply? If each alpha particle deposits 8 * 10^-13 J of energy and if the average person weighs 75 kg, calculate the number of rads and rems of radiation in 1 yr from such a level of plutonium.
Open Question
Calculate the mass of octane, C8H18, that must be burned in air to evolve the same quantity of energy as produced by the fusion of 1.0 g of hydrogen in the following fusion reaction: 4 1^1H → 4 2He + 2 0^1e. Assume that all the products of the combustion of octane are in their gas phases. Use data from Exercise 21.50, Appendix C, and the inside covers of the text. The standard enthalpy of formation of octane is -250.1 kJ/mol.
Open Question
Naturally found uranium consists of 99.274% 238U, 0.720% 235U, and 0.006% 234U. As we have seen, 235U is the isotope that can undergo a nuclear chain reaction. Most of the 235U used in the first atomic bomb was obtained by gaseous diffusion of uranium hexafluoride, UF6(g). (a) What is the mass of UF6 in a 30.0-L vessel of UF6 at a pressure of 695 torr at 350 K? (b) What is the mass of 235U in the sample described in part (a)? (c) Now suppose that the UF6 is diffused through a porous barrier and that the change in the ratio of 238U and 235U in the diffused gas can be described by Equation 10.23. What is the mass of 235U in a sample of the diffused gas analogous to that in part (a)? (d) After one more cycle of gaseous diffusion, what is the percentage of 235UF6 in the sample?
Open Question
Charcoal samples from Stonehenge in England were burned in O2, and the resultant CO2 gas bubbled into a solution of Ca(OH)2 (limewater), resulting in the precipitation of CaCO3. The CaCO3 was removed by filtration and dried. A 788-mg sample of the CaCO3 had a radioactivity of 1.5 × 10^-2 Bq due to carbon-14. By comparison, living organisms undergo 15.3 disintegrations per minute per gram of carbon. Using the half-life of carbon-14, 5700 years, calculate the age of the charcoal sample.