(a) Use data in Appendix C to estimate the boiling point of benze...

Question

(a) Use data in Appendix C to estimate the boiling point of benzene, C6H6. (b) Use a reference source, such as the CRC Handbook of Chemistry and Physics, to find the experimental boiling point of benzene.

Accepted Answer

Step 1: Identify the relevant thermodynamic data for benzene from Appendix C, such as the standard enthalpy of vaporization ($ \Delta H_{vap}^\circ $) and the standard entropy of vaporization ($ \Delta S_{vap}^\circ $).. Step 2: Use the Clausius-Clapeyron equation to relate the enthalpy and entropy of vaporization to the boiling point. The equation is $ \Delta G = \Delta H_{vap}^\circ - T \Delta S_{vap}^\circ $, where $ \Delta G = 0 $ at the boiling point.. Step 3: Rearrange the equation to solve for the boiling point temperature $ T $: $ T = \frac{\Delta H_{vap}^\circ}{\Delta S_{vap}^\circ} $.. Step 4: Substitute the values of $ \Delta H_{vap}^\circ $ and $ \Delta S_{vap}^\circ $ from Appendix C into the equation to calculate the estimated boiling point of benzene.. Step 5: Compare the estimated boiling point with the experimental value found in a reference source, such as the CRC Handbook of Chemistry and Physics, to evaluate the accuracy of the estimation.