Chapter 16, Problem 68c
The hypochlorite ion, ClO-, acts as a weak base. (b) When ClO- acts as a base, which atom, Cl or O, acts as the proton acceptor? (c) Can you use formal charges to rationalize your answer to part (b)?
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Citric acid, which is present in citrus fruits, is a triprotic acid (Table 16.3). (a) Calculate the pH of a 0.040 M solution of citric acid. (b) Did you have to make any approximations or assumptions in completing your calculations? (c) Is the concentration of citrate ion 1C6H5O7 3-2 equal to, less than, or greater than the H+ ion concentration?
Consider the base hydroxylamine, NH2OH. (a) What is the conjugate acid of hydroxylamine?
The hypochlorite ion, ClO-, acts as a weak base. (a) Is ClO- a stronger or weaker base than hydroxylamine?
Write the chemical equation and the Kb expression for the reaction of each of the following bases with water: (a) propylamine, C3H7NH2
Write the chemical equation and the Kb expression for the reaction of each of the following bases with water: (c) benzoate ion, C6H5CO2-
Ephedrine, a central nervous system stimulant, is used in nasal sprays as a decongestant. This compound is a weak organic base: C10H15ON1aq2 + H2O1l2 Δ C10H15ONH+1aq2 + OH-1aq2 A 0.035 M solution of ephedrine has a pH of 11.33. (a) What are the equilibrium concentrations of C10H15ON, C10H15ONH+, and OH-?